Thermally Induced Intramolecular Diels–Alder Reaction of Furan-Tethered Methylenecyclopropanes [PDF]
MoleculesThe substantial ring strain and activated double bonds render methylenecyclopropanes (MCPs) potential substrates for Diels–Alder (DA) reactions. In this work, we present a thermally induced intramolecular Diels–Alder (IMDA) reaction utilizing furan ...
Qi-Yun Huang +3 more
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DIELS-ALDER ADDITION OF BENZYNE TO N-SUBSTITUTED 2-PYRIDONES.
, 1971 DIELS-ALDER ADDITION OF BENZYNE TO N-SUBSTITUTED 2 ...
ERIC BENJAMIN. SHEININ (7996424)
core +5 more sources
, 2023 Computational study on the catalytic control of endo/exo Diels-Alder reactions by cavity quantum vacuum ...
Angel Rubio +2 more
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Inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions of 4-silylated oxazoles [PDF]
, 2002 4-Silylated oxazoles have been shown to undergo inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions with electron-poor alkynes to generate polysubstituted furans.
Marsden, S.P., Ducept, P.C.
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Intramolecular Imino Diels-Alder Reaction: Progress toward the Synthesis of Uncialamycin [PDF]
, 2009 We herein described an intramolecular imino Diels-Alder reaction promoted with BF3.OEt2/DDQ affording substituted quinolines. Using this procedure, we prepared the chiral quitioline moiety of the uncialamycin, a new enediyne natural ...
Pierre van de Weghe +5 more
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Masked Bisketenes as Diels–Alder Dienes [PDF]
, 2020 2,5-Bis(tert-butyldimethylsilyloxy)furans are established as masked vicinal bisketenes for application as dienes in the Diels–Alder reaction.
Emma, Becroft +4 more
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Exo-selective intermolecular Diels–Alder reaction by PyrI4 and AbnU on non-natural substrates
Communications Chemistry, 2021 Diels-Alderases remain rare in nature, particularly those catalysing intermolecular reactions. Here two natural Diels-Alderases are shown to catalyse exo-selective intermolecular Diels-Alder reactions on non-natural substrates.
Rajnandani Kashyap +8 more
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Diaza-1,3-butadienes as Useful Intermediate in Heterocycles Synthesis
Molecules, 2022 Many heterocyclic compounds can be synthetized using diaza-1,3-butadienes (DADs) as key structural precursors. Isolated and in situ diaza-1,3-butadienes, produced from their respective precursors (typically imines and hydrazones) under a variety of ...
Jorge Heredia-Moya +3 more
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Screening of chiral Diels-Alder catalysts by mass spectrometric monitoring of the retro reaction [PDF]
, 2007 A rapid screening procedure for the identification of chiral Diels-Alder catalysts by ESI MS was developed. Screening of the retro reaction made it possible to indirectly determine the catalyst’s enantioselectivity for the forward, product-forming ...
Teichert, Antje Maria
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Highly Regio-, Enantio-, and Exo-selective Diels–Alder Reactions Enabled by a Bispyrrolidine Diboronate [PDF]
, 2021 Catalytic asymmetric Diels−Alder reaction is one of the most powerful reactions in organic chemistry. It is still a challenge to achieve high and general exo-selectivity.
Jia-Hua, Chen +6 more
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