Results 151 to 160 of about 77,395 (287)
Preserving Hierarchical Integrity During Primary Structure Modification of Spherulitic MOFs
A MOF‐74‐type zinc framework self‐organizes into well‐defined spherulitic superstructures while allowing precise covalent post‐synthetic modification (PSM) of the linkers. A built‐in tetrazine enables fast inverse electron‐demand Diels–Alder (iEDDA) functionalization to uniformly install primary amines.
Gabriela Kowacz +2 more
wiley +1 more source
Thermoreversible Diels-Alder Crosslinked Networks in Recycled Poly(ethylene terephthalate) for Reprocessability and Self-Healing. [PDF]
Liu Y +6 more
europepmc +1 more source
Monomer prefunctionalization of upconversion nanoparticles directs uniform growth of BODIPY‐based conjugated porous polymers shells, affording precise control over polymer loading and optimized NIR‐triggered photocatalytic activity. ABSTRACT The great applications of upconversion nanoparticles (UCNPs) can be further extended by their encapsulation ...
Teresa Naranjo +6 more
wiley +1 more source
Synthesis of Spiro-Bridged 3,4-Dihydrocoumarins Through an Organocatalytic Cascade Sequence Diels-Alder/Nucleophilic Ring Closing. [PDF]
Medina-Ortíz A +4 more
europepmc +1 more source
A groundbreaking dual‐donor crosslinking strategy was reported to significantly enhance the thermal stability, achieving remarkable EO coefficients (257–301 pm/V), glass transition temperatures (Tg) ranging from 107–187°C, and ultrahigh chromophore densities (3.73–4.26 × 10²⁰ molecules/cm³) with exceptional long‐term stability after 500 h at 85°C ...
Yu Zhang +7 more
wiley +1 more source
Stable Vicinal Bisketene Equivalents for Aryne Diels-Alder Reactions. [PDF]
Budwitz JE, Newton CG.
europepmc +1 more source
Inverse Diels‐Alder Cycloaddition Reaction was developed for ultrasensitive miR‐21 detection. Based on the enhanced Through‐Bond Energy Transfer and catalytic amplification, it shows a detection limit of 3.58 × 10−18 M and 100 aM–100 nM linear range. It enables high‐contrast cell/tissue imaging and distinguishes lung cancer patients in serum, promising
Yikun Li +10 more
wiley +1 more source
On the Role of Hydrogen Bond Strength and Charge Transfer in an On-Water Diels-Alder Reaction: Semiempirical and Free Energy Calculations. [PDF]
Henao A, Gohar Y, Wilhelm R, Kühne TD.
europepmc +1 more source
Oxaziridines: Versatile Reagents in Modern Organic Synthesis
Being capable of transferring an O atom and N‐group/atom, oxaziridines are considered multitasking agents. These are employed for diverse organic transformations, such as epoxidation of olefins, α‐ and γ‐hydroxylation/amination of carbonyl compounds, oxidation of sulfides, [3+2]cycloaddition with unsaturated systems.
Ajeet Chandra +2 more
wiley +1 more source
Palladium‐Catalyzed Annulations of an Anti‐Bredt Olefin
We report metal‐catalyzed trappings of a [2.2.1]‐bridged bicyclic anti‐Bredt olefin (ABO). The methodology yields unusual heterocyclic products and is expected to prompt the further development of unconventional reactions, including metal‐catalyzed processes of ABOs and other strained olefins. ABSTRACT A famous class of alkene‐containing compounds that
Zach G. Walters +3 more
wiley +2 more sources

