Results 91 to 100 of about 2,240,218 (271)

An Integrated Building Block for Cascade Diels–Alder and Hetero-Diels–Alder Reactions

open access: yes, 2022
The Diels–Alder (DA) reaction and hetero-Diels–Alder (HDA) reaction are among the most powerful methods for the construction of carbocycles and heterocycles. Herein, an integrated building block of DA and HDA reactions is described.
Shuheng Xu (11009858)   +5 more
core   +1 more source

Estudos sobre o uso do NbCl5 como ácido de Lewis em reações de Povarov

open access: yesOrbital: The Electronic Journal of Chemistry, 2011
RESUMO: O objetivo deste trabalho foi investigar o uso de NbCl5 como ácido de Lewis em reações de cicloadição (Reação Aza-Diels-Alder (Povarov)) entre bases de Schiff e éteres enólicos.
Luiz Carlos Silva-Filho, Mayara Frenhe
doaj   +1 more source

A mechanistic study of the Diels-Alder reaction of isoprene with some substitutes benzalmalononitriles

open access: yes, 1980
This work was a kinetic study of the Diels-Alder reaction of isoprene with variously substituted benzalmalononitriles. Application of the Hammett equation, a linear free energy relationship, to the kinetic rate data yielded a value of 1.31 for rho.
Copp, James D.
core  

o-Fluoranil Chemistry: Diels–Alder versus Hetero-Diels–Alder Cycloaddition

open access: yes, 2016
The title quinone undergoes [4 + 2] cycloadditions in two ways, Diels–Alder on the ring and hetero-Diels–Alder by attack at the oxygens. The latter mode of reaction is strongly favored thermodynamically, but there is a kinetic bias favoring the normal ...
John Shellito (2440546)   +2 more
core   +1 more source

Enantio- and Periselective Nitroalkene Diels-Alder Reactions Catalyzed by Helical-Chiral Hydrogen Bond Donor Catalysts

open access: yesMolecules, 2013
Helical-chiral double hydrogen bond donor catalysts promote the nitroalkene Diels-Alder reaction in an enantio- and periselective manner. This represents the first asymmetric catalytic nitroalkene Diels-Alder reaction via LUMO-lowering catalysis. To gain
Zhili Peng   +2 more
doaj   +1 more source

Fluorophobic Acceleration of Diels−Alder Reactions

open access: yes, 2016
Fluorophobic Acceleration of Diels−Alder ...
Kathleen E. Myers (2982246)   +1 more
core   +1 more source

Recent Applications of the Diels-Alder Reaction in the Synthesis of Natural Products (2017-2020)

open access: yes, 2021
The Diels-Alder reaction has long been established as an extremely useful procedure in the toolbox of natural product chemists. It tolerates a wide spectrum of building blocks of different complexity and degrees of derivatization, and enables the ...
Kalesse, Markus   +3 more
core   +1 more source

Anthracen- und Anthrachinon-Oligomere mit ortho-Cyclophanverknüpfung durch wiederholte Diels-Alder-Reaktion von 1,2,5,6-Tetra-exo-methylencyclooctan

open access: yesCHIMIA, 1988
The design of efficient organic electron acceptors requires oligomeric and polymeric hydrocarbons in which separate redox-active units are connected in a sterically variable fashion.
Manfred Wagner   +2 more
doaj   +1 more source

Enantioselective Diels-Alder Reaction Catalyzed by G-Quadruplex DNA and Its Metalloenzyme

open access: yes, 2012
Enantioselective Diels-Alder Reaction Catalyzed by G-Quadruplex DNA and Its ...
卢胜梅   +6 more
core  

One-Pot Three-Component Tandem Metathesis/Diels−Alder Reaction

open access: yes, 2016
A tandem enyne, diene-ene metathesis reaction followed by Diels−Alder reaction accomplished a stereoselective three-component reaction protocol with four ...
Hee-Yoon Lee (165448)   +4 more
core   +1 more source

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