Crystal structure of diethyl (E)-2-[(benzofuran-2-yl)methylidene]succinate
Acta Crystallographica Section E: Crystallographic Communications, 2015 The title compound, C17H18O5, was synthesized by a base-free catalytic Wittig reaction. The molecule consists of a diethyl itaconate unit, which is connected via the C=C double bond to a benzofuran moiety. The benzofuran ring system (r.m.s. deviation = 0.
Marie-Luis Schirmer +2 more
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Machine learnt patterns in rhodium-catalysed asymmetric Michael addition using chiral diene ligands
Results in Chemistry, 2022 Interpretable featurisation allows Quantitative Structure-Property Relationships (QSPR) between chiral diene ligand structures and product stereoselectivities in rhodium-catalysed asymmetric Michael additions (RhCASA).
Benjamin Owen +4 more
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[4 + 2] Cycloadditions of diphenylketene with a highly substituted 1,3-diene [PDF]
, 1987 Diphenylketene (2) undergoes [4 + 2] cycloadditions with the s-cis fixed diene (1) to give the dihydropyran (3) and the cyclohexenone (4)
Heigl, Ulrich W., Mayr, Herbert
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Reactivity of (1-methoxycarbonylpentadienyl)iron(1+) cations with hydride, methyl, and nitrogen nucleophiles [PDF]
, 2017 The reaction of tricarbonyl and (dicarbonyl)triphenylphosphine (1-methoxycarbonyl-pentadientyl)iron(1+) cations 7 and 8 with methyl lithium, NaBH3CN, or potassium phthalimide affords (pentenediyl)iron complexes 9a-c and 11a-b, while reaction with ...
Anobick Sar +58 more
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Research progress in modification of natural rubber/ethylene-propylene diene monomer blending rubber
Hecheng xiangjiao gongye, 2022 The reason for poor compatibility and poor covulcanization of natural rubber and ethylene-propylene diene monomer was systematically summarized, and the technological development in blending modification of natural rubber/ethylene-propylene diene monomer
CHENG An-ren; JIAO Yang; LU Yong-jun; GUO Yue-ying; WANG Lian-cai; DAI Pei
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The Metallacyclopentane-Olefin Interchange Reaction [PDF]
, 1977 Tris(triphenylphosphine)tetramethylenenickel(II) and biscyclopentadienyltetramethylenetitanium, prepared from the reaction of a 1,4-dilithiobutane and the transition metal dihalides react with olefins to produce substituted metallacyclopentanes; the ...
Grubbs, Robert H., Miyashita, Akira
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Beilstein Journal of Organic Chemistry, 2013 The tin(IV)-catalyzed reaction of β-nitrostyrene with (E)-3-methyl-1,3-pentadiene in toluene afforded two major nitronic ester cycloadducts in 27% and 29% yield that arise from the reaction at the less substituted diene double bond.
Peter A. Wade +3 more
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Research progress in catalytic system of ethylene/conjugated diene copolymerization
Hecheng xiangjiao gongye, 2023 The copolymerization techniques of ethylene and conjugated diene, such as butadiene and isoprene, were summarized. The structure and performance characteristics of polymers obtained from different catalytic systems were reviewed with 26 references.
SHEN He-yu1,2, LI Mei1, XU Jin-guo1, LIANG Sheng-biao1, TAO Jie1, HAO Xing-tian1
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Crystal structure of (η2,η2-cycloocta-1,5-diene)(η5-indenyl)cobalt(I)
IUCrData, 2016 The title compound, [Co(C8H12)(C9H7)], was synthesized by the reaction of metallated 2-H-indene with CoCl(PPh3)3 and 1,5-cyclooctadiene in tetrahydrofuran/toluene.
Phillip Jungk +2 more
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Stereodivergent, Diels-Alder-initiated organocascades employing α,β-unsaturated acylammonium salts: scope, mechanism, and application. [PDF]
, 2017 Chiral α,β-unsaturated acylammonium salts are novel dienophiles enabling enantioselective Diels-Alder-lactonization (DAL) organocascades leading to cis- and trans-fused, bicyclic γ- and δ-lactones from readily prepared dienes, commodity acid chlorides ...
Abbasov, Mikail E +3 more
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