Results 81 to 90 of about 103,808 (305)

Technology frontier, labor productivity and economic growth: Evidence from OECD countries [PDF]

open access: yes
We use 29 OECD countries data spanning over 1960-2000 to study the growth strategy when countries are close to the technology frontier. Relying on a semi-parametric generalized additive model, we estimate labor productivity equations.
Azomahou, Theophile   +2 more
core  

Network-analysis-guided synthesis of weisaconitine D and liljestrandinine. [PDF]

open access: yes, 2015
General strategies for the chemical synthesis of organic compounds, especially of architecturally complex natural products, are not easily identified. Here we present a method to establish a strategy for such syntheses, which uses network analysis.
Gallego, GM   +8 more
core   +2 more sources

Thiophenderivate als vielseitige Vorstufen für die Synthese von (Hetero)aromaten und Naturstoffen

open access: yesAngewandte Chemie, EarlyView.
Verborgen, aber leistungsstark: Thiophene und ihre gesättigten Analoga haben sich als vielseitige C4‐Bausteine erwiesen, die sich effektiv in der Naturstoffsynthese sowie beim Aufbau funktionalisierter (Hetero)aromaten einsetzen lassen. Dieser Minireview soll einen Überblick über Strategien zur Anwendung dieser schwefelhaltigen heterozyklischen ...
Anna Keimer, Franz‐Lucas Haut
wiley   +1 more source

A Radical Cascade with Double Intramolecular Hydrogen Atom Transfer for the Generation of Bisfunctionalized Cyclopentanes from Linear Alkynes

open access: yesAngewandte Chemie, EarlyView.
A radical cascade process involving the activation of two aliphatic C–H bonds in a series of five elementary steps converts readily available terminal alkynes into functionalized cyclopentylmethyl arylsulfones. The methodology delivers flexible synthetic intermediates and was applied to the preparation of diquinanes and triquinanes possessing a rare ...
Lise Benoist   +4 more
wiley   +2 more sources

Emission and Cytotoxicity of Surgical Smoke: Cholesta-3,5-Diene Released from Pyrolysis of Prostate Tissue

open access: yesAtmosphere, 2018
Respiratory and lung irritants can be a by-product of the surgical pyrolysis of human tissues. Seven prostate tissues were collected during the transurethral resection of a prostate (TURP).
Min-Suk Bae   +5 more
doaj   +1 more source

The Oxidative state of LDL is the major determinant of anti/prooxidant effect of coffee on Cu2+ catalysed peroxidation [PDF]

open access: yes, 2011
Antioxidants exert contrasting effect on low density lipoprotein (LDL) oxidation catalysed by metals, acting as pro-oxidants under select in vitro conditions.
Carru, Ciriaco   +9 more
core  

Vielseitiger und selektiver Biomolekül‐Pulldown mit kombinatorischen DNA‐quervernetzten Polymeren

open access: yesAngewandte Chemie, EarlyView.
Wir stellen ein programmierbares Polymersystem für die universelle, sequenzselektive Bioseparation unter nativen Bedingungen vor. Eine Polymerphasentrennung wird durch kombinatorische DNA‐Vernetzung erreicht, wodurch DNA, RNA oder Proteine in homogener Lösung mit hoher Pulldown‐Effizienz und vernachlässigbarer Hintergrundbindung eingefangen werden ...
Sarah K. Speed   +3 more
wiley   +1 more source

Copper‐Catalyzed Three‐Component Selective 1,4‐Amino Oxygenation of 1,3‐Dienes

open access: yesAngewandte Chemie, EarlyView.
Enclosed is a copper‐catalyzed selective 1,4‐amino oxgenation of 1,3‐dienes with the presence of a strong Brønsted acid. This three‐component transformation offers a novel and powerful approach to construct (E)‐1,4‐allylic amino oxygenated motifs by the simultaneous installation of structurally diverse alkylamines and alcohols directly onto 1,3‐dienes.
Guangshou Feng   +2 more
wiley   +2 more sources

Preparation, Characterization and Reactivity of (3-Methylpentadienyl)iron(1+) Cations [PDF]

open access: yes, 2007
The title cations (9 and 12) were prepared by dehydration of (3-methyl-2,4-pentadien-1-ol)Fe(CO)2L+ complexes. The structure of the (CO)2PPh3-ligated 12 was determined by single-crystal X-ray analysis. Reaction of carbon and heteroatom nucleophiles to (3-
Bennett, Dennis W   +5 more
core   +1 more source

Salzcluster mit Oberflächen‐Defekt zeigt ungewöhnliche Säure‐Base‐Chemie

open access: yesAngewandte Chemie, EarlyView.
Die Austauschreaktion von Ameisensäure an Meersalz‐Aerosolen, bei der HCl freigesetzt wird, fordert die herkömmliche Säure‐Base‐Chemie heraus. Unsere Gasphasenversuche zeigen, dass diese Reaktion an reinen NaCl‐Clusterionen in Abwesenheit von Wasser stattfindet.
Jessica C. Hartmann   +7 more
wiley   +1 more source

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