On the hydrolysis of diethyl 2-(perfluorophenyl)malonate [PDF]
Beilstein Journal of Organic Chemistry, 2020 Diethyl 2-(perfluorophenyl)malonate was synthesized in 47% isolated yield by the reaction of sodium diethyl malonate and hexafluorobenzene. The resulting compound was considered as a starting material for synthesizing 2-(perfluorophenyl)malonic acid by ...
Ilya V. Taydakov, Mikhail A. Kiskin
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Volumetric, viscometric and optical study of molecular interactions in binary mixtures of diethyl malonate with ketones at 303.15, 308.15 and 313.15K [PDF]
Journal of the Serbian Chemical Society, 2012 Density ρ, viscosity η, and refractive index nD were measured for the binary mixtures of diethyl malonate with ketones (acetophenone, cyclopentanone, cyclohexanone and 3-pentanone) at temperatures (303.15, 308.15 and 313.15) K over the entire ...
Rathnam Manapragada V. +2 more
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Crystal structure and identification of resonance forms of diethyl 2-(3-oxoiso-1,3-dihydrobenzofuran-1-ylidene)malonate [PDF]
Acta Crystallographica Section E: Crystallographic Communications, 2017 The reaction of diethyl malonate with phthaloyl chloride in acetonitrile in the presence of triethylamine and magnesium chloride results in the formation of the title compound, diethyl 2-(3-oxo-1,3-dihydro-2-benzofuran-1-ylidene)propanedioate, C15H14O6 ...
Mikhail S. Tyumentsev +3 more
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Diethyl 2-[(4-bromoanilino)methylidene]malonate [PDF]
Acta Crystallographica Section E, 2010 In the title compound, C14H16BrNO4, intermolecular C—H...O hydrogen bonds link the molecules, forming a stable structure. An intramolecular N—H...O hydrogen bond results in the formation of a six-membered ring and helps to establish ...
Huai-Qing Wang +4 more
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Diethyl 2-{[(4-methoxy-3-pyridyl)amino]methylidene}malonate [PDF]
Acta Crystallographica Section E, 2011 In the title molecule, C14H8N2O5, the amino group is involved in the formation an intramolecular N—H...O hydrogen bond. In the crystal, weak intermolecular C—H...O and C—H...N hydrogen bonds link the molecules into ribbons ...
Zhi-Fang Zhang
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Diethyl Malonate-Based Turn-On Chemical Probe for Detecting Hydrazine and Its Bio-Imaging and Environmental Applications With Large Stokes Shift [PDF]
Frontiers in Chemistry, 2021 Diethyl malonate-based fluorescent probe NE-N2H4 was constructed for monitoring hydrazine (N2H4). The novel probe NE-N2H4 exhibits good properties, such as large Stokes shift (about 125 nm), good selectivity, and low cytotoxicity.
Jianbo Qu +4 more
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Reactivity of vanadium oxytrichloride with β-diketones and diesters as precursors for vanadium nitride and carbide [PDF]
Materials & Design, 2016 Vanadium(V) oxytrichloride was reacted with 2,4-pentanedione, diethyl malonate, and diethyl succinate under inert conditions, forming compounds: dichloro(oxo)(2,4-pentanedione) vanadium(V) [1], dichloro(oxo)(diethyl malonate) vanadium(IV) [2] and ...
Ben J. Blackburn +8 more
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Unnatural α-amino ethyl esters from diethyl malonate or ethyl β-bromo-α-hydroxyiminocarboxylate [PDF]
Beilstein Journal of Organic Chemistry, 2018 We have explored here the scope of the age-old diethyl malonate-based accesses to α-amino esters involving Knoevenagel condensations of diethyl malonate on aldehydes, reductions of the resulting alkylidenemalonates, the preparation of the corresponding α-
Eloi P. Coutant +5 more
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Diethyl 2-(triphenylmethyl)malonate [PDF]
Acta Crystallographica Section E, 2008 In the title compound, C26H26O4, steric crowding of the Ph3C– group with the –CH(CO2Et)2 unit leads to a long C—C bond [1.585 (2) Å]. One of the two ethyl groups is disordered over two sites in a 60:40 ratio.
Xian-You Yuan, Min Zhang, Seik Weng Ng
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Diethyl 2-(2-nitrobenzylidene)malonate [PDF]
Acta Crystallographica Section E, 2009 In the title compound, C14H15NO6, the ethoxycarbonyl groups adopt extended conformations. In the crystal, molecules are linked into centrosymmetric dimers via pairs of C—H...O hydrogen bonds with a R22(20) motif.
S. Thenmozhi +4 more
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