Results 101 to 110 of about 8,721 (248)
Diethyl 2-[(morpholin-4-yl)(phenyl)methyl]malonate
In the title compound, C18H25NO5, the morpholine unit adopts an almost ideal chair conformation. The crystal structure is consolidated by C—H⋯O intermolecular hydrogen-bond interactions, providing stabilization. The molecular conformation shows two possible pockets ready to coordinate two metal atoms.
Akkurt, Mehmet+5 more
openaire +4 more sources
Ring transformations in reactions of pyrimidine and N-alkylpyrimidinium salts with nucleophile [PDF]
Paper IOn treatment with liquid ammonia at -33°C, the quaternary pyrimidinium salts, i.e. 1-methylpyrimidinium methyl sulfate, 1,2-dimethylpyrimidinium iodide, 1,4,6-trimethyl-pyrimidinium iodide and 1,2,4,6-tetramethylpyrimidinium iodide demethylate ...
Oostveen, E.A.
core +1 more source
Synthesis of carbon-13-labeled tetradecanoic acids.
The synthesis of tetradecanoic acid enriched with 13C at carbons 1, 3, or 6 is described. The label at the carbonyl carbon was introduced by treating 1-bromotridecane with K13CN (90% enriched) to form the 13C-labeled nitrile, which upon hydrolysis ...
J T Sparrow, K M Patel, J D Morrisett
doaj +1 more source
A series of 6,8-diiodocoumarin-3-N-carboxamides (4–11) were prepared. Treatment of ethyl 6,8-diiodocoumarin-3-carboxylate (1) with ethyl cyanoacetate/NH4OAc gave ethyl 2-(3-carbamoyl-6,8-diiodocoumarin-4-yl)-2-cyanoacetate (12) and 2-amino-4-hydroxy-7,9 ...
Hany M. Mohamed+6 more
doaj +1 more source
Phase change indicators for subambient temperatures [PDF]
Evaluation of organic compounds for temperature indicators for subambient ...
Kasanof, D. R., Kimmel, E.
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Lactone Carboxylic Acids. III. Reaction of Ethyl β-Alkylglycidates with Ethyl Malonate [PDF]
The ring opening of epoxide group in the reaction of ethyl ,β-alkylglycidates with sodiomalonate was observed mostly at the α-position of the glycidates.
Kariya, Yosihiro+2 more
core +1 more source
Synthesis of 3a,12a-dihydroxy-23a,23b-dihomo-5b-cholan-24-oic acid [PDF]
A novel multi-step synthesis of 3a,12a-dihydroxy-23a,23b-dihomo-5b-cholan-24-oic acid (23a,23b-dihomodeoxycholic acid) (5) has been achieved from methyl 3a,12a-dihydroxy-5b-cholanoate (1).
SLAVKO KEVRESAN+3 more
doaj
6-(2-Chlorobenzyl)-1-(4-chlorophenyl)-7-hydroxy-2,3-dihydro-1H-imidazo[1,2-a]pyrimidin-5-one
The title compound, C19H15Cl2N3O2, was obtained by a one-step cyclocondensation of 2-amino-1-(4-chlorophenyl)imidazoline with diethyl (2-chlorobenzyl)malonate under basic conditions.
Waldemar Wysocki+5 more
doaj +1 more source
Lactone Carboxylic Acids. IV. Reaction of Ethyl Chloroarylpyruvate with Ethyl Malonate [PDF]
The condensation of ethyl chloroarylpyruvate (Ⅰ) with ethyl malonate in the presence of sodium ethoxide afforded γ-aryl-α,β-dicarbethoxy-⊿(β),γ-butenolide.
Takeda, Akira+2 more
core +1 more source