Acute environmental toxicity and persistence of DEM, a chemical agent simulant: Diethyl malonate. [Diethyl malonate] [PDF]
The purpose of the following chemical simulant studies is to assess the potential acute environmental effects and persistence of diethyl malonate (DEM). Deposition velocities for DEM to soil surfaces ranged from 0.04 to 0.2 cm/sec. For foliar surfaces, deposition velocities ranged from 0.0002 cm/sec at low air concentrations to 0.05 cm/sec for high ...
D.A. Cataldo+6 more
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Diethyl 2-{[(4-methoxy-3-pyridyl)amino]methylidene}malonate [PDF]
In the title molecule, C14H8N2O5, the amino group is involved in the formation an intramolecular N—H...O hydrogen bond. In the crystal, weak intermolecular C—H...O and C—H...N hydrogen bonds link the molecules into ribbons ...
Zhi-Fang Zhang
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Diethyl 2-{4-diethylamino-2-[(dimethylcarbamothioyl)oxy]benzylidene}malonate [PDF]
In the title compound, C21H30N2O5S, the plane of the dimethyl–thiocarbamic group makes a dihedral angle of 78.41 (7)° with the central benzene ring. One of the carbonyl groups in the α,β-unsaturated malonate
Dan Sun+3 more
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(η5-Cyclopentadienyl)[η6-diethyl ethyl(phenyl)malonate]iron(II) hexafluoridophosphate [PDF]
At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C5H5)(C15H20O4)]PF6, are almost parallel [dihedral angle between planes = 4.10 (14)°].
Hilary A. Jenkins+2 more
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Preparation of diethyl malonate adducts from chalcone analogs containing a thienyl ring [PDF]
Nine chalcone-diethyl malonate derivatives (4a-i) were prepared by the reaction of chalcone derivatives (3a-i) with diethyl malonate in the presence of a catalytic amount of KOt-Bu in CH2CI2 in good to excellent yields. The products were characterized by
Budak, Yakup+3 more
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Diethyl 2-{(dibenzylamino)[4-(trifluoromethyl)phenyl]methyl}malonate [PDF]
The asymmetric unit of the title compound, C29H30F3NO4, contains two independent molecules. In each independent molecule, one of two terminal ethyl groups is disordered over two conformations: the occupancies of major components were fixed at 0.53 and 0 ...
Ihssan Meskini+4 more
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Rate of tritium exchange in diethyl methyl-d3-malonate-t and diethyl malonate-d,t in buffered aqueous solutions [PDF]
Abstract
O. Gjurović-Deletis+2 more
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Diethyl 2,2-bis(3,5-di-tert-butyl-4-hydroxybenzyl)malonate [PDF]
The title molecule, C37H56O6, possesses twofold symmetry, with the twofold axis passing through the quaternary C atom. In the crystal, neighbouring molecules are linked via O—H...O hydrogen bonds involving the phenol OH group and the carbonyl O
Tao Zeng+3 more
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Diethyl 2-{[3-(2-methoxybenzyl)thiophen-2-yl]methylidene}malonate [PDF]
In the title compound, C20H22O5S, the dihedral angle between the mean planes through the thiophene and benzene rings is 75.2 (1)°. The methoxy group is essentially coplanar with the benzene ring, the largest deviation from the mean ...
S. Ranjith+4 more
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Synthesis of designed new 1,3,4-oxadiazole functionalized pyrano [2,3-f] chromene derivatives and their antimicrobial activities [PDF]
Diethyl 2-(((4-methyl-2-oxo-2H-chromen-7-yl)oxy)methylene)malonate (2) was synthesized from coumarin 1 and diethyl ethoxymethylene malonate in ethanol, followed by cyclization in diphenyl ether to give chromene-9-carboxylate (3).
Kahdr Alatawi+7 more
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