Reaction of β-Nitrostyrene with Diethyl Malonate in the Presence of Bispidines: The Unusual Role of the Organocatalyst [PDF]
The aim of this work was the investigation of novel organocatalysts for the Michael addition of diethyl malonate to β-nitrostyrene. The methodology of the study included NMR titration, reaction monitoring by NMR spectroscopy and electrospray ionization ...
Alexander I. Dalinger +4 more
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Crystal structure of diethyl 2-(((2-(pyridin-3-ylthio)phenyl)amino)methylene)malonate, C19H20N2O4S
C19H20N2O4S, monoclinic, P21/c, a = 18.983(4) Å, b = 5.057(1) Å, c = 20.304(4) Å, β = 106.10(3)°, V = 1872.7(7) Å3, Z = 4, Rgt(F) = 0.0680, wRref(F2) = 0.1423, T = 293(2) K.
Meng-Xue Wang, Zheng Fang, Kai Guo
doaj +2 more sources
Synthesis of Diethyl 2-(2-chloronicotinoyl)malonate [PDF]
Qi-Dong Tang +5 more
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DIETHYL MALONATE IS BASIC FOR BARBITURATES [PDF]
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Catalytic and Photoluminescence Properties of the First- and Second-Sphere Coordination of Lanthanide Complexes. [PDF]
The Michael donor and the Michael acceptor are activated via hydrogen bonding interactions within the second‐sphere coordination of europium complexes. Abstract The efficient binding of receptors Lk (Lk = L5‐L8) to [Eu(hfac)3] (H‐hfac = 1,1,1,5,5,5‐hexafluoropentane‐2,4‐dione) allows (i) to gather the basic unit‐containing tridentate ligands Lk and the
Le-Hoang G +4 more
europepmc +2 more sources
Thermal Decomposition of Isocyanate Diethyl Malonate Adducts
Toshio AGAWA, Toru MINAMI, Saburo KOMORI
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Crystal structure of diethyl 2-(2-methyl-5-nitrothiazol- 4-ylmethylene)malonate, C12H14N2O6S [PDF]
Crozet M. D. +3 more
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Available in Commercial Quantities...Diethyl Malonate [PDF]
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Dearomative Nucleophilic Addition of Lithium Enolates to Electron-Poor Indoles. [PDF]
Electrophilic electron‐depleted indoles undergo 1,4‐addition to afford the dearomatized products, with complete diastereoselectivity, after smooth hydrolysis. While 3‐nitroindoles readily furnish the corresponding nitroindolines, α‐ketoamide indoles show a more complex reactivity, undergoing either 1,2‐ or 1,4‐addition, depending on the steric ...
Roseau M +4 more
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