Unimolecular Reactions of Diethyl Malonate Cation in Gas-phase
Journal of the Mass Spectrometry Society of Japan, 2004 Unimolecular reactions of diethyl malonate cation (CH3CH2OC(=O)CH2C(=O)OCH2CH3+· ; 1+·, Mw : 160) induced by electron ionization, have been investigated by use of mass-analyzed ion kinetic energy (MIKE) spectrometry and D-labeling in conjunction with thermochemistry.
Susumu Tajima +3 more
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Diethyl 2-[(5-methoxy-2-methyl-1-phenylsulfonyl-1H-indol-3-yl)methylene]malonate [PDF]
Acta Crystallographica Section E, 2009 In the title compound, C24H25NO7S, the sulfonyl-bound phenyl ring is approximately perpendicular to the indole ring system [dihedral angle = 87.72 (5)°].
T. Kavitha +4 more
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Diethyl 2-[(4-nitrophenyl)(4-phenyl-1,2,3-selenadiazol-5-yl)methyl]malonate [PDF]
Acta Crystallographica Section E, 2008 In the title compound, C22H21N3O6Se, the heterocyclic ring makes dihedral angles of 50.03 (11) and 67.75 (11)°, respectively, with the benzene and phenyl rings.
Nigam P. Rath +4 more
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Diethyl 2-[(2-benzyl-1-phenylsulfonyl-1H-indol-3-yl)methylene]malonate [PDF]
Acta Crystallographica Section E, 2009 In the title compound, C29H27NO6S, the sulfonyl-bound phenyl ring is almost perpendicular to the indole ring system [dihedral angle = 87.96 (6)°], while the benzylphenyl ring is oriented at an angle of 76.8 (7)°. An intramolecular C&
T. Kavitha +4 more
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Reaction of β-Nitrostyrene with Diethyl Malonate in the Presence of Bispidines: The Unusual Role of the Organocatalyst [PDF]
ChemistryThe aim of this work was the investigation of novel organocatalysts for the Michael addition of diethyl malonate to β-nitrostyrene. The methodology of the study included NMR titration, reaction monitoring by NMR spectroscopy and electrospray ionization ...
Alexander I. Dalinger +4 more
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A Simple Method for the Alkylation of Diethyl Malonate
Journal of Japan Oil Chemists' Society, 1974 Shota Itô +3 more
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Reactivity of δ-Functionalized Para-Quinone Methides in Nucleophilic Addition Reactions. [PDF]
ChemistryThe reactivities of δ‐functionalized para‐quinone methides (pQMs) were characterized by kinetic studies of their reactions with carbanions in DMSO. Evaluating the second‐order rate constants (k2) by the Mayr‐Patz equation gave the electrophilicities E of pQMs.
Gross C, Eitzinger A, Mayer P, Ofial AR.
europepmc +2 more sources
Crystal structure of diethyl 2-(2-methyl-5-nitrothiazol- 4-ylmethylene)malonate, C12H14N2O6S [PDF]
Zeitschrift für Kristallographie - New Crystal Structures, 2005 Crozet M. D. +3 more
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A novel diethyl 2-(9-fluorenyl) malonate functionlized SBA-15 for selective optical sensing of Iron [PDF]
Journal of Nanostructures, 2019 In this study, highly ordered mesoporous silica material (SBA-15) functionalized with Diethyl 2 - (9 -fluorenyl) malonate as a flourophore is reported.
Alireza Badiei +2 more
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Synthesis of novel β-aminocyclobutanecarboxylic acid derivatives by a solvent-free aza-Michael addition and subsequent ring closure [PDF]
, 2011 Novel beta-aminocyclobutanecarboxylic acid derivatives were prepared via a sequential solvent-free aza-Michael addition of benzophenone imine across 3-halopropylidenemalonates and base-induced ring closure.
Aitken +44 more
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