Synthesis and Characterization of New Chelating Resins Containing Thiourea as the Functional Group [PDF]
A senes of chelating resins, derived from a macroreticular styrenedivinylbenzene (2%) copolymer beads grafted with various spacer from propylene groups (-CH₂-CH₂-CH₂)n (n=1, 2, 4) and containing thiourea as chelating function, have been synthesized in
Mohd Amin, Mohd Shaberi
core
Nonproductive Events in Ring-Closing Metathesis Using Ruthenium Catalysts [PDF]
The relative TONs of productive and nonproductive metathesis reactions of diethyl diallylmalonate are compared for eight different ruthenium-based catalysts. Nonproductive cross metathesis is proposed to involve a chain-carrying ruthenium methylidene.
Grubbs, Robert H.+4 more
core +2 more sources
Nanoporous aluminosilicate-catalyzed telescoped acetalization-direct aldol reactions of acetals with 1,3-dicarbonyl compounds [PDF]
Nanoporous aluminosilicate materials, synthesized by an evaporation-induced self-assembly process, catalyze the direct aldol reaction of acyclic acetals with a range of 1,3-dicarbonyl compounds to produce the corresponding aldol addition products in high
Davies, Thomas Edward+2 more
core +4 more sources
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist [PDF]
Tables of ^1H and ^(13)C NMR chemical shifts have been compiled for common organic compounds often used as reagents or found as products or contaminants in deuterated organic solvents.
Bercaw, John E.+7 more
core +1 more source
Oxidative halogenation of cisplatin and carboplatin: synthesis, spectroscopy, and crystal and molecular structures of Pt(IV) prodrugs [PDF]
A series of Pt(IV) prodrugs has been obtained by oxidative halogenation of either cisplatin or carboplatin. Iodobenzene dichloride is a general reagent that cleanly provides prodrugs bearing axial chlorides without the need to prepare intervening Pt(IV ...
Alexander, Sarah M.+3 more
core +1 more source
In search for highly bioactive barbituric and thiobarbituric acid derivatives, some new barbituric and thiobarbituric acids bearing 1,2,4-triazine moiety and their related systems (5–13) have been obtained from the addition of isocyanate and ...
Abeer N. Al-Romaizan
doaj +1 more source
Polyoxometalate-intercalated layered double hydroxides as efficient and recyclable bi-functional catalysts for cascade reactions [PDF]
The polyoxometalate (POM) intercalated-layered double hydroxides (LDHs) have been widely used as heterogeneous catalysts. However, the application of POM-LDHs as bi-functional catalysts for cascade reaction has seldom been studied comparing with the ...
Angelescu+41 more
core +1 more source
Malonylation/Decarbalkoxylation of Furan Derivatives as Key Steps for the Preparation of Nonactic Acid Derivatives. Part I [1] [PDF]
Summary.: A malonylation/decarbalkoxylation sequence from 2-substituted furans was investigated in view of developing a scalable synthesis of hydrophobic nonactic acid ...
Bobal, Pavel+5 more
core +1 more source
Diastereoselective conjugate addition of (R)-4-phenyl-2-oxazolidinone to dialkyl alkylidenemalonates [PDF]
International audienceThe addition of the potassium salt of (R)-4-phenyl-2-oxazolidinone to dialkyl alkylidenemalonates under various conditions is reported. Very good diastereoselectivities (> 90% de) were obtained in several cases. Conversion of one of
Capra, Julien+4 more
core +2 more sources
Enantioselective Synthesis of Dialkylated N-Heterocycles by Palladium-Catalyzed Allylic Alkylation [PDF]
The enantioselective synthesis of α-disubstituted N-heterocyclic carbonyl compounds has been accomplished using palladium-catalyzed allylic alkylation.
Houk, K. N.+4 more
core +2 more sources