Results 181 to 190 of about 1,944,422 (285)

A Conserved Isoleucine Gates the Diffusion of CO and O2 to the Active Site of NiFe CO‐Dehydrogenase

open access: yesAngewandte Chemie, EarlyView.
A combination of protein film electrochemistry and site‐directed mutagenesis shows that isoleucine 563 (numbering of Thermococcus sp. AM4) gates the arrival of both CO and O2 to the active site of the nickel‐iron CO dehydrogenases. Mutations at this position increase the resistance to O2 at the cost of a slower reaction with CO.
Laura Opdam   +7 more
wiley   +2 more sources

Direct Observation of Radical‐Mediated Oxide‐to‐Alloy Transformation in Solution Under Pulsed Laser Irradiation

open access: yesAngewandte Chemie, EarlyView.
Time‐resolved in situ x‐ray absorption spectroscopy and DFTB‐based molecular dynamics simulations identify direct hydrogen atom transfer from ethanol to lattice oxygen as the elementary step of laser‐driven reduction in NiCo2O4. While this transfer is facile, the subsequent release of lattice oxygen is entropy‐driven and becomes accessible only at ...
Woo Hyeok Kim   +12 more
wiley   +2 more sources

Dissipative Regenerative Chemiluminescence in Water: A Perylene‐Based Out‐of‐Equilibrium Light‐Emitting System

open access: yesAngewandte Chemie, EarlyView.
Driven by sodium dithionite and hydrogen peroxide under mild aqueous conditions, a water‐soluble perylene bisimide undergoes reversible electron‐transfer cycles that generate its emissive excited state without dye decomposition. We define this out‐of‐equilibrium system as chemically fueled regenerative chemiluminescence (CFRCL), opening new avenues for
Luca Morgan   +5 more
wiley   +2 more sources

A Novel Electrochemical Sensor Based on r-GO@SiC Nanocomposite Materials for the Highly Sensitive Detection of Metronidazole. [PDF]

open access: yesMolecules
Bakytkarim Y   +7 more
europepmc   +1 more source

Home - About - Disclaimer - Privacy