Results 11 to 20 of about 22,756 (205)

A non-carboxylating pentose bisphosphate pathway in halophilic archaea

open access: yesCommunications Biology, 2022
A nucleoside degradation pathway in halophilic archaea is identified, which converts the ribose moiety of guanosine to dihydroxyacetone phosphate and ethylene glycol.
Takaaki Sato   +13 more
doaj   +1 more source

Selective oxidation of glycerol to dihydroxyacetone using CeO2-ZrO2-Bi2O3-SnO2-supported platinum catalysts

open access: yesJournal of Asian Ceramic Societies, 2020
The effects of the Bi3+ introduction and the oxygen release and storage abilities on selective oxidation of glycerol into dihydroxyacetone (DHA) were demonstrated using Pt/CeO2-ZrO2-Bi2O3-SnO2/SBA-16 (SBA-16: Santa Barbara Amorphous No. 16) catalysts. By
Naoyoshi Nunotani   +4 more
doaj   +1 more source

Incorporation of tin into zirconium phosphate to boost efficient conversion of trioses to lactic acid

open access: yesCatalysis Communications, 2023
Dihydroxyacetone isomerization is a fundamental reaction for the production of lactic acid using different feedstocks. However, achieving excellent catalytic activity and resistance against leaching in water is challenging.
Ruite Lai   +9 more
doaj   +1 more source

Predictive control of selective secondary alcohol oxidation of glycerol on NiOOH

open access: yesNature Communications, 2022
While valuable chemicals can be obtained from biomass electro-oxidation, the mechanisms can be challenging to discern. Here, authors show that explicit control of electrochemical dehydrogenation mechanisms enables selective secondary alcohol oxidation of
McKenna K. Goetz   +2 more
doaj   +1 more source

Investigating the effects of dihydroxyacetone on oxidative stress factors and histology of heart and liver tissue in acute aluminum phosphide poisoning

open access: yesمجله علمی دانشگاه علوم پزشکی کردستان, 2023
Background and Aim: Aluminum phosphide poisoning has a high mortality rate because of the production of phosphine gas and refractory hypotension. Based on the effect of dihydroxyacetone on the treatment of hypotension and reduction of cytochrome C ...
jafar ahmadi   +5 more
doaj  

Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst

open access: yesNature Communications, 2021
Radicals-mediated Fenton chemistry has the potential for biomass valorization. Here, inspired from the natural goethite mineral, the authors develop a MnO2/goethite catalyst showing excellent yields of glycolic acid and formic acid from dihydroxyacetone,
Jinling Wang   +8 more
doaj   +1 more source

Efficient glycerol transformation by resting Gluconobacter cells

open access: yesMicrobiologyOpen, 2019
In the present work, glycerol biotransformation using Gluconobacter strains was studied with a process intensification perspective that facilitated the development of a cleaner and more efficient technology from those previously reported.
Erienne Jackson   +2 more
doaj   +1 more source

Sugar analog synthesis by in vitro biocatalytic cascade: A comparison of alternative enzyme complements for dihydroxyacetone phosphate production as a precursor to rare chiral sugar synthesis. [PDF]

open access: yesPLoS ONE, 2017
Carbon-carbon bond formation is one of the most challenging reactions in synthetic organic chemistry, and aldol reactions catalysed by dihydroxyacetone phosphate-dependent aldolases provide a powerful biocatalytic tool for combining C-C bond formation ...
Carol J Hartley   +10 more
doaj   +1 more source

Ketal Protection of Glycerol for Selective Electrosynthesis of Glyceric Acid in Highly Alkaline Media

open access: yesAngewandte Chemie, EarlyView.
Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang   +6 more
wiley   +2 more sources

Valorization of Waste Glycerol to Dihydroxyacetone with Biocatalysts Obtained from Gluconobacter oxydans

open access: yesApplied Sciences, 2018
Waste glycerol is the main by-product generated during biodiesel production, in an amount reaching up to 10% of the produced biofuel. Is there any method which allows changing this waste into industrial valuable compounds?
Lidia Stasiak-Różańska   +2 more
doaj   +1 more source

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