Results 11 to 20 of about 22,756 (205)
A non-carboxylating pentose bisphosphate pathway in halophilic archaea
A nucleoside degradation pathway in halophilic archaea is identified, which converts the ribose moiety of guanosine to dihydroxyacetone phosphate and ethylene glycol.
Takaaki Sato +13 more
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The effects of the Bi3+ introduction and the oxygen release and storage abilities on selective oxidation of glycerol into dihydroxyacetone (DHA) were demonstrated using Pt/CeO2-ZrO2-Bi2O3-SnO2/SBA-16 (SBA-16: Santa Barbara Amorphous No. 16) catalysts. By
Naoyoshi Nunotani +4 more
doaj +1 more source
Dihydroxyacetone isomerization is a fundamental reaction for the production of lactic acid using different feedstocks. However, achieving excellent catalytic activity and resistance against leaching in water is challenging.
Ruite Lai +9 more
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Predictive control of selective secondary alcohol oxidation of glycerol on NiOOH
While valuable chemicals can be obtained from biomass electro-oxidation, the mechanisms can be challenging to discern. Here, authors show that explicit control of electrochemical dehydrogenation mechanisms enables selective secondary alcohol oxidation of
McKenna K. Goetz +2 more
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Background and Aim: Aluminum phosphide poisoning has a high mortality rate because of the production of phosphine gas and refractory hypotension. Based on the effect of dihydroxyacetone on the treatment of hypotension and reduction of cytochrome C ...
jafar ahmadi +5 more
doaj
Radicals-mediated Fenton chemistry has the potential for biomass valorization. Here, inspired from the natural goethite mineral, the authors develop a MnO2/goethite catalyst showing excellent yields of glycolic acid and formic acid from dihydroxyacetone,
Jinling Wang +8 more
doaj +1 more source
Efficient glycerol transformation by resting Gluconobacter cells
In the present work, glycerol biotransformation using Gluconobacter strains was studied with a process intensification perspective that facilitated the development of a cleaner and more efficient technology from those previously reported.
Erienne Jackson +2 more
doaj +1 more source
Sugar analog synthesis by in vitro biocatalytic cascade: A comparison of alternative enzyme complements for dihydroxyacetone phosphate production as a precursor to rare chiral sugar synthesis. [PDF]
Carbon-carbon bond formation is one of the most challenging reactions in synthetic organic chemistry, and aldol reactions catalysed by dihydroxyacetone phosphate-dependent aldolases provide a powerful biocatalytic tool for combining C-C bond formation ...
Carol J Hartley +10 more
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Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang +6 more
wiley +2 more sources
Waste glycerol is the main by-product generated during biodiesel production, in an amount reaching up to 10% of the produced biofuel. Is there any method which allows changing this waste into industrial valuable compounds?
Lidia Stasiak-Różańska +2 more
doaj +1 more source

