Results 231 to 240 of about 197,285 (307)

The Nitration of Veratraldehyde Dimer and Acetylvanillin Dimer

open access: yesNippon kagaku zassi, 1968
Yoshimori OMOTE   +2 more
openaire   +2 more sources

Heat‐ and Light‐Directed Cycloadditions Enable a Pericyclic Cascade Reaction From a Molecular Precursor

open access: yesAngewandte Chemie, EarlyView.
A multi‐stimuli‐responsive material is designed that responds to light, heat, and mechanical force through distinct chemical reaction pathways. The pathway is directed by self‐assembly and the applied stimulus. A novel pericyclic reaction cascade is also achieved, and the mechanism is supported through density functional theory calculations.
Liulei Ma   +4 more
wiley   +1 more source

Axially Chiral Nonalternant Polycyclic Aromatic Hydrocarbon With Consecutive Pentagons Exhibiting Large Spin‐Polarized Current

open access: yesAngewandte Chemie, EarlyView.
Here we report two nonalternant polycyclic aromatic hydrocarbons (PAH) (1 and 2), which contain two and four consecutive pentagons, respectively. Under acidic conditions, 1 and 2 dimerize to afford the axially chiral dimers AC1 and AC2. The central azulene moiety in both 2 and AC2 shows an unusually short transannular bond of 1.366 Å.
Chang Wang   +3 more
wiley   +1 more source

1,3‐Brook Rearrangement of α‐Silyl Allylic Alcohols: Copper‐Catalyzed Enantiospecific Formation of Allenes and Copper‐Mediated ipso‐Substitution Reactions Affording Trisubstituted Alkenes

open access: yesAngewandte Chemie, EarlyView.
A regioselective ruthenium catalyzed trans‐hydrosilylation of propargyl alcohols followed by a 1,3‐Brook rearrangement opens access to reactive organocopper intermediates, which evolve upon warming into allenes with strict chirality transfer to the emerging axis; alternatively, these reactive species can be trapped with a large variety of electrophiles
Jack L. Sutro   +3 more
wiley   +1 more source

Biosynthesis of O-Prenylated Chaetophenols Triggers Nonenzymatic Pathways toward Structural Diversity. [PDF]

open access: yesOrg Lett
Matsui H   +8 more
europepmc   +1 more source

Scalable ω‐Substituted α‐Olefins via Living Chain Transfer Telomerization: A Platform for Next Generation Polyolefins

open access: yesAngewandte Chemie, EarlyView.
A highly versatile and general strategy is presented for the scalable production of practical quantities of ω‐substituted α‐olefins using tris(ω‐substituted alkyl)aluminum telogens that are readily available through a “green” synthesis from commodity triisobutylaluminum and ethene as the taxogen. These new α‐olefins can be designed and used as monomers
Lauren G. Logue   +4 more
wiley   +1 more source

Impact of Lysine-Mediated C-Terminal Dimerization of Anoplin on Killing Kinetics and Antibiotic Interaction Profiles. [PDF]

open access: yesMicroorganisms
Ferreira SRR   +6 more
europepmc   +1 more source

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