Reactions of Terminal Olefins With Iron Carbenes
Iron carbenes react with terminal olefins and show productive metathesis or metathesis‐divergent pathways depending on the nature of the olefin. Reactions proceed through 2π + 2π cycloadditions to generate transient metallacyclobutane intermediates that undergo cycloreversion to generate the metathesis product or the metathesis‐divergent β‐hydride ...
Zachary S. Lincoln +2 more
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Oncogenic EGFR mutants differentially alter dimerization, adaptor protein engagement, and clathrin-mediated internalization. [PDF]
Bello-Hassan M, Singh PK, Smith AW.
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Suppression of Peierls Instability in a Metal−Halide Porous Framework
Peierls distortion in one‐dimensional Pt‐I chains is suppressed by confinement within the periodic electrostatic environment of a porous Cu–I framework. X‐ray crystallography shows equivalent Pt–I distances without bond alternation, and conductivity of the Pt‐I chains is greatly enhanced.
Ning Zhou +3 more
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Regulation of the endoplasmic reticulum stress sensor ATF6α through multiple oxidoreductases in the ER. [PDF]
Wada S, Uegaki K, Nagata K, Ushioda R.
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Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
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Sulfur‐Boron Lewis Pair‐Catalyzed Hydrohalogenation of Alkynes via Formal Hydrogen Atom Transfer
A sulfur‐boron Lewis pair enables the stereodivergent hydrohalogenation of alkynes with exclusive Markovnikov selectivity. Mechanistic studies support a proton transfer‐electron transfer (PT‐ET) sequence for vinyl radical formation rather than a concerted hydrogen atom transfer (HAT) pathway.
Yun Soo Shim +4 more
wiley +1 more source
Membrane affinity difference between MinD monomer and dimer is not crucial for MinD gradient formation in <i>Bacillus subtilis</i>. [PDF]
Bohorquez LC +5 more
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Structures of DnaA domain I reveal a dimer conserved across Actinomycetes. [PDF]
Ellis PK +5 more
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Rather than selecting dopants to match a pre‐existing host matrix, the dopant‐tailored matrix strategy involves rational engineering of host matrices around a preselected class of dopants by targeting matrix packing motifs that promote synergistic host‐dopant interactions upon doping.
Catherine Demangeat +7 more
wiley +1 more source
A De Novo Peptide That Induces Axonal Growth Through TrkB Activation. [PDF]
Maini R +4 more
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