Dimethyl Carbonate: Green Solvent and Ambident Reagent [PDF]
DMC is a versatile compound which represents an attractive ecofriendly alternative to both methyl halides (or dimethyl sulfate) and phosgene for methylation and carbonylation processes, respectively. DMC, produced nowadays by a clean process, possesses properties of no toxicity and biodegradability which makes it a true green reagent to be used in ...
TUNDO, Pietro +4 more
openaire +2 more sources
Solvent effects on Grubbs’ pre-catalyst initiation rates [PDF]
Initiation rates for Grubbs and Grubbs-Hoveyda second generation pre-catalysts have been measured accurately in a range of solvents. Solvatochromic fitting reveals different dependencies on key solvent parameters for the two pre-catalysts, consistent ...
Abboud +33 more
core +1 more source
Carbon dioxide (an abundant, inexpensive, and renewable carbon resource) is one of the most significant greenhouse gases that cause global warming and climate changes.
Oscar Arbelaez +5 more
doaj +1 more source
Fluid phase equilibria of the reacting mixture in the dimethyl carbonate synthesis from supercritical CO2 [PDF]
In order to investigate the dimethyl carbonate synthesis from methanol and supercritical CO2, the thermodynamic behaviour of the reacting mixture, i.e. the quaternary methanol/CO2/DMC/water mixture, has to be known.
Badens, François +3 more
core +2 more sources
Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid
Energy demand is increasing dramatically because of the fast industrial development, rising population, and economic growth in the world. To fulfill this energy demand, a large amount of fuel is widely used from different fossil resources.
Balaji Panchal +5 more
doaj +1 more source
Feasibility of Batch Reactive Distillation with Equilibrium-Limited Consecutive Reactions in Rectifier, Stripper, or Middle-Vessel Column. [PDF]
A general overall feasibility methodology of batch reactive distillation of multireaction systems is developed to study all the possible configurations of batch reactive distillation.
Lelkes, Zoltan +4 more
core +4 more sources
The future of isosorbide as a fundamental constituent for polycarbonates and polyurethanes
Isosorbide is a biobased compound which could become in the near future an advantageous competitor of petroleum-derived components in the synthesis of polymers of different nature.
Olga Gómez-de-Miranda-Jiménez-de-Aberasturi +11 more
doaj +1 more source
Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts [PDF]
The syntheses of a range of enantiopure organosulfur donors with hydrogen bonding groups are described including TTF related materials with two, four, six and eight hydroxyl groups and multiple stereogenic centres and a pair of chiral N-substituted BEDT ...
Akutsu, H +11 more
core +1 more source
Synergy Effect of High-Stability of VS4 Nanorods for Sodium Ion Battery
Sodium-ion batteries (SIBs) have attracted increasing interest as promising candidates for large-scale energy storage due to their low cost, natural abundance and similar chemical intercalation mechanism with lithium-ion batteries.
Yi Chen +6 more
doaj +1 more source

