Results 71 to 80 of about 43,472 (265)

Solvent Effects on the Conformational Preferences of 2,6‐Pyridylcarboxamide Foldamers

open access: yesChemistry – A European Journal, EarlyView.
The marked effect of organic solvents and water/methanol mixtures on the conformational preferences of a soluble chiral foldamer has been established in a diverse array of seventeen distinct environments. ABSTRACT The marked influence of organic solvents and water on the conformational preferences of a chiral, soluble 2,6‐pyridylcarboxamide foldamer ...
Alexander R. Davis   +5 more
wiley   +1 more source

Catalyst‐Free Cyanation of Arenes by Acetonitrile in a Plasma–Liquid Microreactor

open access: yesChemistry – A European Journal, EarlyView.
An original approach of arylnitrile synthesis was developed by generating an argon plasma in contact with solutions of arene in acetonitrile within a gas‐liquid microreactor. Plasma activation of acetonitrile generated cyano radicals, enabling a catalyst‐free C‐H cyanation of arenes.
Pierre Dedieu   +4 more
wiley   +1 more source

A Simple Regeneration Process Using a CO2‐Switchable‐Polarity Solvent for Cellulose Hydrogels

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The effect of transformation of the anion chemical structure on cellulose solubility by flowing CO2 gas into aqueous pyrrolidinium hydroxide solutions was investigated. The changes in anion structure allowed for the modulation of cellulose solubility in aqueous pyrrolidinium hydroxide solutions, thus establishing a simple and safe cellulose ...
Arata Matsui   +5 more
wiley   +1 more source

Crystal structure of phenarsazine chloride dimethylsulfoxide solvate, C14H15AsClNOS

open access: yesZeitschrift für Kristallographie - New Crystal Structures, 2021
C14H15AsClNOS, monoclinic, P21 (no. 4), a = 5.2852(2) Å, b = 13.3035(6) Å, c = 10.7522(5) Å, β = 90.130(2) Å, V = 756.00(6) Å3, Z = 2, Rgt(F) = 0.0200, wRref(F2) = 0.0503, T = 200(2) K.
Averdunk Arthur   +2 more
doaj   +1 more source

Bidirectional sleep‐seizure interactions and orexin in a mouse model of tuberous sclerosis complex‐related epilepsy

open access: yesEpilepsia, EarlyView.
Abstract Objective A strong bidirectional relationship exists between epilepsy and sleep, with seizures often occurring more frequently in sleep and, in turn, sleep being disrupted by seizures. However, the mechanistic basis of seizure–sleep interactions is poorly understood.
Nicholas R. Rensing   +4 more
wiley   +1 more source

Structural and Functional Bis(dithiolene)-Molybdenum/Tungsten Active Site Analogues of the Dimethylsulfoxide Reductase Enzyme Family

open access: yes, 2016
Structural and Functional Bis(dithiolene)-Molybdenum/Tungsten Active Site Analogues of the Dimethylsulfoxide Reductase Enzyme ...
Kie-Moon Sung (2719129)   +2 more
core   +1 more source

Reactivity of β-Stannylketones. Elimination vs. Substitution

open access: yesMolecules, 2000
In the present work we report the results obtained in the reaction of β-stannylketones (I) with t-BuONa in dimethylsulfoxide (DMSO) and acetonitrile (ACN) as solvents. The reaction mechanisms probably involved are proposed.
Ana Paula Murray, Alicia B. Chopa
doaj   +1 more source

Clinical validation of a patient‐friendly saliva microsampling approach to monitor perampanel levels in people with epilepsy

open access: yesEpilepsia, EarlyView.
Abstract Perampanel (PER) is a third‐generation antiseizure medication (ASM) with a well‐established concentration–effect relationship. Saliva represents a non‐invasive alternative to plasma for therapeutic drug monitoring (TDM) of PER, as it reflects the free plasma fraction.
Valentina Franco   +14 more
wiley   +1 more source

The multiple hit model of infantile and epileptic spasms: The 2025 update

open access: yesEpilepsia Open, EarlyView.
Abstract Objective Infantile and epileptic spasms syndrome (IESS) is a developmental and epileptic encephalopathy manifesting with epileptic spasms and poor neurodevelopmental outcomes. There is an urgent need for the development of more effective and tolerated therapies.
Aristea S. Galanopoulou   +6 more
wiley   +1 more source

Dimethylsulfoxide reduction by marine sulfate-reducing bacteria [PDF]

open access: yes, 1996
Dimethylsulfoxide (DMSO) reduction occurred in five out of nine strains of sulfate-reducing bacteria from marine or saline environments, but not in three freshwater isolates. DMSO reduction supported growth in all positive strains.
Jonkers, Henk M.   +3 more
core   +1 more source

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