Results 1 to 10 of about 4,963,210 (228)
Direct Arylation in the Presence of Palladium Pincer Complexes [PDF]
Molecules, 2021 Direct arylation is an atom-economical alternative to more established procedures such as Stille, Suzuki or Negishi arylation reactions. In comparison with other palladium sources and ligands, the use of palladium pincer complexes as catalysts or pre ...
Garazi Urgoitia +4 more
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Rhodium-catalyzed selective direct arylation of phosphines with aryl bromides [PDF]
Nature Communications, 2022 The widespread use of biaryl monophosphines is frequently hampered by the challenges associated with their modular preparation. Here, the authors report a protocol that appends arenes to arylphosphines to access a series of these compounds via rhodium ...
Dingyi Wang +6 more
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Direct Arylation of Simple Arenes with Aryl Bromides by Synergistic Silver and Palladium Catalysis. [PDF]
ACS Catal, 2021 The direct, catalytic arylation of simple arenes in small excess with aryl bromides is disclosed. The developed method does not require the assistance of directing groups and relies on a synergistic catalytic cycle in which phosphine-ligated silver ...
Tlahuext-Aca A +3 more
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Direct Arylation Synthesis of Small Molecular Acceptors for Organic Solar Cells [PDF]
Molecules, 2023 In recent years, small molecular acceptors (SMAs) have extensively promoted the progress of organic solar cells (OSCs). The facile tuning of chemical structures affords SMAs excellent tunability of their absorption and energy levels, and it gives SMA ...
Xiaochen Wang +5 more
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CHIMIA, 2022 Bonds between hydrogen and carbon atoms are the most frequent type of bonds in organic molecules. The ability to replace hydrogen atoms by making other types of bonds to carbon atoms can enable simpler access to complex organic molecules by substituting
Jyoti Dhankhar, Ilija Čorić
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Ag/Pd Cocatalyzed Direct Arylation of Fluoroarene Derivatives with Aryl Bromides. [PDF]
ACS Catal, 2020 Diverse C–H functionalizations catalyzed by Pd employ Ag(I) salts added as halide abstractors or oxidants. Recent reports have shown that Ag can also perform the crucial C–H activation step in several of these functionalizations.
Panigrahi A +3 more
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Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C-H bonds. [PDF]
Chem Sci, 2020 Convergent paired electrosynthesis is an energy-efficient approach in organic synthesis; however, it is limited by the difficulty to match the innate redox properties of reaction partners.
Zhang L, Hu X.
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Room-temperature Pd/Ag direct arylation enabled by a radical pathway [PDF]
Beilstein Journal of Organic Chemistry, 2020 Direct arylation is an appealing method for preparing π-conjugated materials, avoiding the prefunctionalization required for traditional cross-coupling methods. A major effort in organic electronic materials development is improving the environmental and
Amy L. Mayhugh, Christine K. Luscombe
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Direct arylation of strong aliphatic C-H bonds. [PDF]
Nature, 2018 Despite the widespread success of transition-metal-catalysed cross-coupling methodologies, considerable limitations still exist in reactions at sp3-hybridized carbon atoms, with most approaches relying on prefunctionalized alkylmetal or bromide coupling ...
Perry IB +5 more
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“On Water” Palladium Catalyzed Direct Arylation of 1H-Indazole and 1H-7-Azaindazole [PDF]
Molecules, 2020 The C3 direct arylation of 1H-indazole and 1H-7-azaindazole has been a significant challenge due to the lack of the reactivity at this position. In this paper, we describe a mild and an efficient synthesis of new series of C3-aryled 1H-indazoles and C3 ...
Khadija Gambouz +7 more
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