Results 141 to 150 of about 3,271,959 (246)
Use of Polycyclic Aromatic Compounds as Electrophotocatalysts in Organic Reactions
Emerging from the convergence of photoredox catalysis and electrochemistry, electrophotocatalysis is a relatively new and promising synthetic approach in organic chemistry. In this review, the main advantages and the current challenges of this methodology are discussed, while most relevant and late applications of polycyclic aromatic hydrocarbons (PAHs)
Marco Manni +3 more
wiley +1 more source
Tertiary Arsine Ligands for Pd-Catalyzed Direct Arylation
Catalysts for direct arylations have been extensively studied for the efficient synthesis of (hetero)biaryl compounds. Phosphine ligands are pivotal in this field, and electron-deficient phosphine ligands are advantageous for direct arylation. Due to its
Takashi Yumura (1273050) +4 more
core +2 more sources
A zinc single‐atom catalyst anchored on nitrogen‐doped mesoporous carbon (Zn@NMC) was synthesized via an evaporation‐induced self‐assembly method and applied in the one‐pot synthesis of 2,4(5)‐diarylimidazoles. The catalyst was fully characterized using FT‐IR, XRD, SEM, EDX, BET, and TGA analyses.
Maryam Shojaei‐Asl, Mohsen Moradian
wiley +1 more source
Riluzole metabolism guided the design of benzo[d]thiazole inhibitors of casein kinase 1 delta (CK1δ), a kinase linked to amyotrophic lateral sclerosis (ALS). Docking supported ATP site recognition by the hydroxylamine metabolite and hydrazine analogues, leading to compounds showing improved potency and retained predicted blood brain barrier ...
Simone Adorinni +18 more
wiley +1 more source
Transition Metal‐Driven Selectivity in Direct C−H Arylation of Imidazo[2,1‐b]Thiazole
A selective direct arylation of the different Csp2‐H bonds of imidazo[2,1‐b]thiazole with (hetero) aryl halides can be achieved simply by switching from a palladium catalyst system to the use of stoichiometric amounts of copper. The observed selectivity,
Dr. Antonio Del Vecchio +9 more
doaj +1 more source
A practical convergent synthesis of PI3K inhibitor GDC-0908 (1) is described. The process features a dihydrobenzothienooxepine formation via palladium-catalyzed intramolecular direct C–H arylation and a Negishi coupling to construct the key C–C bonds. We
Haiming Zhang +11 more
core +1 more source
Challenges and Perspectives for an Extended Use of the Dye‐Sensitized Solar Cells
DSSC is a photoelectrochemical technology that will support the energy transition. DSSCs initiated the building‐integrated photovoltaics sector and are now proposed in agrivoltaics, archaeophotovoltaics and as indoor solution for powering the Internet of Things. The wavelength selectivity for photoconversion renders DSSCs unique in photovoltaics ambit.
Danilo Dini +6 more
wiley +1 more source
Tris(indol‐3‐yl)methanes were synthesized from indoles, CO2, and PhMe2SiH in the presence of BPh3 in acetonitrile at 50°C. One product, tris(4‐bromo‐1‐methylindol‐3‐yl)methane, underwent a palladium‐catalyzed cascade reaction for the formation of a novel polycyclic heteroaromatic compound, where the methine C(sp3) atom originating from CO2 was ...
Sha Li +5 more
wiley +1 more source
Synthesis, Updated Characterization, and Reactivity of Low‐Valent Titanocene Complexes
Syntheses and characterizations are provided for a series of low‐valent titanocene complexes including halotitanocene(III) dimers, [Cp2Ti(κ2‐DME)][BAr4] cations, and heterobimetallic [Cp2Ti(μ‐Cl)2AlR2]. Additionally, a monomeric titanacyclopropene complex featuring a pendent phosphine was prepared, and C─F bond activation upon reduction of [Cp{η5:κ2F2 ...
Griffin J. LaChapelle +2 more
wiley +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source

