Results 31 to 40 of about 19,002,772 (320)

Copper-mediated oxidative C−H/N−H activations with alkynes by removable hydrazides

open access: yesBeilstein Journal of Organic Chemistry, 2021
The efficient copper-mediated oxidative C–H alkynylation of benzhydrazides was accomplished with terminal alkynes. Thus, a heteroaromatic removable N-2-pyridylhydrazide allowed for domino C–H/N–H functionalization.
Feng Xiong   +7 more
doaj   +1 more source

Synthesis of Polysubstituted Ferrocenesulfoxides

open access: yesMolecules, 2022
The purpose of the study is to design synthetic methodologies, especially directed deprotometalation using polar organometallic reagents, to access polysubstituted ferrocenesulfoxides.
Min Wen   +6 more
doaj   +1 more source

Imine as a linchpin approach for meta-C–H functionalization

open access: yesNature Communications, 2021
Site-selective C–H functionalization still faces some challenges, such as the introduction and removal of an appropriate directing group. Here, the authors introduce a temporary directing group for selective meta-C–H functionalization of 2 ...
Sukdev Bag   +6 more
doaj   +1 more source

Set-direct factorizations of groups [PDF]

open access: yesJournal of Algebra, 2018
referee comments included, 19 ...
Levy, Dan, Maróti, Attila
openaire   +2 more sources

Distal Functionalization via Transition Metal Catalysis

open access: yesChemistry Proceedings, 2022
The ubiquitous presence of sp3 C−H bonds in natural feedstock makes them inexpensive, easily accessible, and attractive synthons for the preparation of common and/or complex molecular frameworks in biologically active natural products, pharmaceutics ...
Haibo Ge
doaj   +1 more source

Transition-metal-catalyzed aromatic C–H functionalization assisted by the phosphorus-containing directing groups

open access: yesGreen Synthesis and Catalysis, 2023
Transition-metal-catalyzed C–H bond functionalization has attracted tremendous attention as an increasingly important protocol for the construction of C–C and C–X bonds.
Jian Zhang   +5 more
doaj   +1 more source

Directing-Group-Free Palladium-Catalyzed C–H Arylation of Aldoxime Using Oxime’s Umpolung Properties

open access: yes, 2022
Alkyl aldoximes without a directing group undergo palladium-catalyzed C–H arylation with aryl bromides to afford alkyl aryl ketoximes in moderate to high yields.
Nobuyoshi Morita (1608451)   +3 more
core   +1 more source

Grouping with Directed Relationships [PDF]

open access: yes, 2001
Grouping is a global partitioning process that integrates local cues distributed over the entire image. We identify four types of pairwise relationships, attraction and repulsion, each of which can be symmetric or asymmetric. We represent these relationships with two directed graphs.
Stella X. Yu, Jianbo Shi
openaire   +1 more source

A directed $d$-group that is not a group of divisibility [PDF]

open access: yesCzechoslovak Mathematical Journal, 1984
The reviewer [Czech. Math. J. 32(107), 77-89 (1982; Zbl 0499.06013)] asked if there exists a directed ordered abelian group which admits a multivalued addition \(\oplus\) satisfying the axioms of d-groups but which is not a group of divisibility of an integral domain. In this note the author constructs such an example.
openaire   +2 more sources

Synthesis of β-arylated alkylamides via Pd-catalyzed one-pot installation of a directing group and C(sp3)–H arylation

open access: yesBeilstein Journal of Organic Chemistry, 2016
The synthesis of β-arylated alkylamides via alkyl C–H bond arylation has been realized by means of direct one-pot reactions of acyl chlorides, aryl iodides and 8-aminoquinoline. Depending on the structure of the starting materials, both single and double
Yunyun Liu   +3 more
doaj   +1 more source

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