Results 51 to 60 of about 19,002,772 (320)

Transition Metal-Catalyzed C-H Activation via Imine-Based Transient Directing Group Strategy

open access: yesYouji huaxue, 2020
In the past decades, transition metal-catalyzed C-H activation has experienced tremendous growth and revolutionized the field of organic synthesis. Several elegant strategies have been developed to promote reactivity and control precise site-selectivity.
Yong-Jin Wu, Bingfeng Shi
semanticscholar   +1 more source

Tuning Reactivity in Pd-Catalysed C(sp3)-H Arylations via Directing Group Modifications and Solvent Selection

open access: yes, 2020
The palladium-catalysed sp3 C-H arylation of a selection of saturated amine scaffolds was investigated using substituted picolinamide directing groups.
Abil, Aliev   +4 more
core   +1 more source

Pd-catalysed ligand-enabled carboxylate-directed highly regioselective arylation of aliphatic acids

open access: yesNature Communications, 2017
Palladium catalysed C-H functionalization ofsp3carbons typically requires the installation and subsequent removal of a temporary directing group. Here the authors report a method allowing C-H functionalization in carboxylic acids in which the carboxylate
Yan Zhu   +5 more
doaj   +1 more source

Insights on tert-butyl alkylation effects on fluorobenzene

open access: yesScientific African, 2021
Directing effects of substituents on the benzene ring, ortho and para directors by electron donating groups and meta directors using electron withdrawing groups have been studied and reported widely. In particular and for many years, the directing effect
Lewis Mtashobya
doaj   +1 more source

Grouping principles in direct competition

open access: yesVision Research, 2013
We (1) introduce a primed flanker task as an objective method to measure perceptual grouping, and (2) use it to directly compare the efficiency of different grouping cues in rapid visuomotor processing. In two experiments, centrally presented primes were succeeded by flanking targets with varying stimulus-onset asynchronies (SOAs).
Schmidt, Filipp, Schmidt, Thomas
openaire   +2 more sources

SOCIOPSYCHODRAMA: Protagonist-centered sociopsychodrama

open access: yesRevista Brasileira de Psicodrama, 2020
Sociopsychodrama, as a group intervention method, enables directing strategies referenced to different approaches that prioritize protagonization, sociometry, or the spontaneous theater, among other probable theories.
Luís Falivene Alves
doaj   +1 more source

Recent Progress in the Synthesis of Benzoxazin-4-Ones, Applications in N-Directed Ortho-Functionalizations, and Biological Significance

open access: yesMolecules
The development of efficient synthetic procedures to access fused N, O-heterocyclic skeletons has been a pivotal research topic in organic synthesis for several years.
Ziad Moussa   +3 more
doaj   +1 more source

The Goldmark's Report directing to the organization of a subsidiary group of nursing (1919-1923)

open access: yesCultura de los Cuidados, 2012
Study about the directings to the organization of a subsidiary group of nursing on the Goldmark’s Report, 1919–1923. The temporal clipping comprehend the 1919 year, when was determined the committee that would conduct the study that resulted on Goldmark ...
Mary Ann Menezes Freire   +3 more
doaj   +1 more source

Electrocatalyzed direct arene alkenylations without directing groups for selective late-stage drug diversification

open access: yesNature Communications, 2023
Electrooxidation has emerged as an increasingly viable platform in molecular syntheses that can avoid stoichiometric chemical redox agents. Despite major progress in electrochemical C−H activations, these arene functionalizations generally require ...
Zhipeng Lin   +11 more
doaj   +1 more source

Selective synthesis of meta-phenols from bio-benzoic acids via regulating the adsorption state

open access: yesiScience, 2023
Summary: Phenols are important building blocks widely applied in many fields. The pronounced orientational effect of the phenolic hydroxyl group makes achieving selective synthesis of meta-phenols challenging.
Xinze Du   +4 more
doaj   +1 more source

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