Results 151 to 160 of about 2,674 (194)

PEGylated Gold Nanoprobe Bearing the Diselenide Bond for ROS-Responsive Fluorescence Imaging

open access: yesMacromolecular Research, 2018
Reactive oxygen species (ROS)-sensitive imaging can be used to distinguish ROS-rich diseased tissues from normal tissues. Herein, we developed a selective H2O2 concentration-dependent on-off gold nanoprobe and demonstrated its in vitro fluorescence imaging application using activated macrophages cells. The nanoprobe was prepared by covalent conjugation
V G Deepagan   +2 more
exaly   +4 more sources
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Healable and Rearrangeable Networks of Liquid Crystal Elastomers Enabled by Diselenide Bonds

Angewandte Chemie - International Edition, 2021
AbstractBased on liquid crystal elastomer (LCE) materials, hierarchically structured soft actuators can meet some requirements for “human‐friendly” working mode and execute complex tasks with intelligent adaptation to environmental changes. However, few researchers have paid much attention to the preparation methods of multicomponent/hierarchical LCE ...
Hari Krishna Bisoyi   +2 more
exaly   +3 more sources

Chalcogen Bonds in Crystals of Bis(o-anilinium)diselenide Salts

open access: yesCrystal Growth & Design, 2018
The diselenide moiety is labeled as a novel and robust chalcogen bond (ChB) donor group. The molecular electrostatic potential of two prototype diselenide derivatives shows the presence of two σ-holes along both the covalent bonds in which each selenium atom is involved.
Scilabra P.   +3 more
openaire   +3 more sources

Oxidation of diselenide bond with sodiumtetracloroaurate (III): Significance in chemotherapy

Inorganic Chemistry Communication, 2005
Abstract Gold(III) reacts with selenocystamine (diselenide) and immediately breaks the diselenide-bond as observed by 13C NMR spectroscopy. It is also observed that diselenide is more reactive to gold(III) compare to its analogous disulfide (cystamine) molecule. The results are compared with similar diselenide and disulfide molecule with other gold(I)
Anvarhusein A ISAB
exaly   +2 more sources

Dual-Responsive Polyphosphoester-Doxorubicin Prodrug Containing a Diselenide Bond: Synthesis, Characterization, and Drug Delivery

open access: yesACS Biomaterials Science & Engineering, 2018
The development of novel stimuli-responsive and biodegradable polyphosphoester-anticancer prodrugs is of importance in designing water-soluble prodrugs utilized in the field of drug delivery. In this study, the focus is on the synthesis of biocompatible and biodegradable diselenide-containing polyphosphoester [PEEP-b-PBYP-Se]2 using reduction ...
Guoqing Ma   +4 more
openaire   +3 more sources

When Dynamic Diselenide Bonds Meet Dynamic Imine Bonds in Polymeric Materials

Macromolecular Rapid Communications, 2022
AbstractIn both natural and artificial functional systems, the cooperation between different dynamic interactions is of vital importance for realizing complicated functions. Dynamic covalent bonds are one kind of relatively stable dynamic interactions and have shown synergistic effect in natural systems such as functional proteins. However, synergistic
Muqing Cao   +4 more
openaire   +2 more sources

Chalcogen Bonding Induced Tetraselenides from Twisted Diselenides

European Journal of Inorganic Chemistry, 2020
The first sterically controlled oxidation of mesoionic selone using copper(II) salt was demonstrated. The present methodology gave access to a rare tetraselenide from dimerized diselenides through chalcogen bonding (ChB). Besides, a similar approach with sterically less crowded mesoionic triazole selone, 1‐(2‐mesitylene)‐3‐methyl‐4‐phenyltriazolin‐5 ...
Moulali Vaddamanu, Ganesan Prabusankar
openaire   +2 more sources

Influence of reduction-sensitive diselenide bonds and disulfide bonds on oligoethylenimine conjugates for gene delivery

J. Mater. Chem. B, 2014
As a new reduction-sensitive linkage, diselenide bonds can also timely release DNA inside the tumor cells, while remaining constant outside the cells, implying its higher stability during the circulation process and great potential for in vivo gene delivery system design.
Dong, Yue   +6 more
openaire   +2 more sources

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