Results 1 to 10 of about 4,443 (117)

Electrochemical Synthesis of 3-Selenyl-Chromones via Domino C(sp2)-H Bond Selenylation/Annulation of Enaminones [PDF]

open access: yesMolecules
Herein, we disclose a highly efficient pathway toward 3-selenylated chromone derivatives via electrosynthesis domino C(sp2)-H bond selenylation/cyclization/deamination of 2-hydroxyaryl enaminones with diselenides. This method showed mild conditions, easy
João M. Brito   +12 more
doaj   +2 more sources

Diselenide-bridged hybrid mesoporous silica for radiosensitization and radioprotection in the radioimmunotherapy of colorectal cancer [PDF]

open access: yesJournal of Nanobiotechnology
Radioimmunotherapy has been recognized as a promising strategy for the treatment of colorectal cancer; however, it faces several challenges, including limited efficacy, weak immune activation, and severe radiation-induced colitis. To address these issues,
Fan Zhang   +12 more
doaj   +2 more sources

Synthesis and Application Dichalcogenides as Radical Reagents with Photochemical Technology

open access: yesMolecules, 2023
Dichalcogenides (disulfides and diselenides), as reactants for organic transformations, are important and widely used because of their potential to react with nucleophiles, electrophilic reagents, and radical precursors.
Cairong Wang   +5 more
doaj   +1 more source

Exploring of the property of epoxy resins based on diselenide and disulfide dynamic linkers

open access: yesFrontiers in Chemistry, 2022
Over the last decade, there has been a lot of interest in incorporating dynamic covalent bonds (DCBs) into epoxy resins. Because diselenide and disulfide bonds have similar properties, they are frequently used as DCBs in self-healing epoxy networks.
Xiao Wei   +7 more
doaj   +1 more source

Redox-Responsive Comparison of Diselenide and Disulfide Core-Cross-Linked Micelles for Drug Delivery Application

open access: yesPharmaceutics, 2023
In this study, diselenide (Se–Se) and disulfide (S–S) redox-responsive core-cross-linked (CCL) micelles were synthesized using poly(ethylene oxide)2k-b-poly(furfuryl methacrylate)1.5k (PEO2k-b-PFMA1.5k), and their redox sensitivity was compared. A single
Sonyabapu Yadav   +8 more
doaj   +1 more source

Aerial Oxygen-Driven Selenocyclization of O-Vinylanilides Mediated by Coupled Fe3+/Fe2+ and I2/I Redox Cycles

open access: yesMolecules, 2022
In the past decade, selenocyclization has been extensively exploited for the preparation of a wide range of selenylated heterocycles with versatile activities.
Hao-Yuan Zhang   +6 more
doaj   +1 more source

Structural reorganization and crack-healing properties of hydrogels based on dynamic diselenide linkages

open access: yesScience and Technology of Advanced Materials, 2020
We report the dynamic behavior of diselenide-containing hydrophilic polyurethanes and hydrogels based on diselenide exchange reactions in an aqueous media.
Hao Xu   +6 more
doaj   +1 more source

New Amides and Phosphoramidates Containing Selenium: Studies on Their Cytotoxicity and Antioxidant Activities in Breast Cancer

open access: yesAntioxidants, 2021
Breast cancer is a multifactor disease, and many drug combination therapies are applied for its treatment. Selenium derivatives represent a promising potential anti-breast cancer treatment.
Mikel Etxebeste-Mitxeltorena   +8 more
doaj   +1 more source

Reactive Human Plasma Glutathione Peroxidase Mutant with Diselenide Bond Succeeds in Tetramer Formation

open access: yesAntioxidants, 2022
Plasma glutathione peroxidase (GPx3) belongs to the GPx superfamily, and it is the only known secreted selenocysteine (Sec)−containing GPx in humans.
Zhenlin Fan   +3 more
doaj   +1 more source

Versatile Electrochemical Synthesis of Selenylbenzo[b]Furan Derivatives Through the Cyclization of 2-Alkynylphenols

open access: yesFrontiers in Chemistry, 2022
We report an electrochemical oxidative intramolecular cyclization reaction between 2-alkynylphenol derivatives and different diselenides species to generate a wide variety of substituted-benzo[b]furans.
Carlos V. Doerner   +13 more
doaj   +1 more source

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