Results 71 to 80 of about 390,267 (298)

Quantum chemical studies of redox properties and conformational changes of a four-center iron CO2 reduction electrocatalyst. [PDF]

open access: yes, 2018
The CO2 reduction electrocatalyst [Fe4N(CO)12]- (abbrev. 1-) reduces CO2 to HCO2- in a two-electron, one-proton catalytic cycle. Here, we employ ab initio calculations to estimate the first two redox potentials of 1- and explore the pathway of a side ...
Berben, Louise A   +5 more
core   +2 more sources

AAA+ protein unfoldases—the Moirai of the proteome

open access: yesFEBS Letters, EarlyView.
AAA+ unfoldases are essential molecular motors that power protein degradation and disaggregation. This review integrates recent cryo‐electron microscopy (cryo‐EM) structures and single‐molecule biophysical data to reconcile competing models of substrate translocation.
Stavros Azinas, Marta Carroni
wiley   +1 more source

Latest News: Reactions of Group 4 Bis(trimethylsilyl)acetylene Metallocene Complexes and Applications of the Obtained Products

open access: yesChemistryOpen, 2021
Recently published reactions of group 4 metallocene bis(trimethylsilyl)acetylene (btmsa) complexes from the last two years are reviewed. Complexes like Cp’2Ti(η2‐Me3SiC2SiMe3) and Cp2Zr(py)(η2‐Me3SiC2SiMe3) with Cp’ as Cp (cyclopentadienyl) and Cp ...
Prof. Uwe Rosenthal
doaj   +1 more source

Dissociative Recombination: building and destroying aspects in interstellar chemistry

open access: yesJournal of Physics: Conference Series, 2011
We discuss the ionic composition of the interstellar molecular gas. Particular emphasis is put on the halogenic ions such as H2Cl+ and H2F+ for which no DR studies have been published up to now.
Evelyne Roueff, Eric Herbst
openaire   +1 more source

pH‐mediated activation of the lysosomal arginine sensor SLC38A9

open access: yesFEBS Letters, EarlyView.
Cells monitor nutrient levels via the lysosomal transporter SLC38A9 to activate the mechanistic target of rapamycin complex 1 (mTORC1). This study reveals that SLC38A9 function is regulated by pH. We identified histidine 544 as a critical pH sensor that undergoes conformational changes to control amino acid efflux from lysosomes; therefore, it ...
Xuelang Mu, Ampon Sae Her, Tamir Gonen
wiley   +1 more source

Free charges versus excitons: photoluminescence investigation of InGaN/GaN multiple quantum well nanorods and their planar counterparts [PDF]

open access: yes, 2018
InGaN/GaN multiple quantum well (MQW) nanorods have demonstrated significantly improved optical and electronic properties compared to their planar counterparts.
Chen, W.   +10 more
core   +1 more source

Residual tail twisting in ascidian larvae is stabilized by asymmetric myofibrils that resist bilateral symmetry restoration

open access: yesFEBS Letters, EarlyView.
Ascidian Ciona larvae initially show strong clockwise tail twisting, which is largely corrected during development. However, a small residual twist remains. This study shows that organized helical myofibrils in tail muscles mechanically stabilize this residual asymmetry, preventing complete restoration of bilateral symmetry and revealing how embryos ...
Yuki S. Kogure   +3 more
wiley   +1 more source

Linearized Coupled Cluster Correction on the Antisymmetric Product of 1 reference orbital Geminals

open access: yes, 2015
We present a Linearized Coupled Cluster (LCC) correction based on an Antisymmetric Product of 1 reference orbital Geminals (AP1roG) reference state. In our LCC ansatz, the cluster operator is restricted to double and to single and double excitations as ...
Ayers, Paul W., Boguslawski, Katharina
core   +2 more sources

Phenotypic and genotypic characterization of single circulating tumor cells in the follow‐up of high‐grade serous ovarian cancer

open access: yesMolecular Oncology, EarlyView.
Single circulating tumor cells (sCTCs) from high‐grade serous ovarian cancer patients were enriched, imaged, and genomically profiled using WGA and NGS at different time points during treatment. sCTCs revealed enrichment of alterations in Chromosomes 2, 7, and 12 as well as persistent or emerging oncogenic CNAs, supporting sCTC identity.
Carolin Salmon   +9 more
wiley   +1 more source

Density Functional Theory Investigations on the Mechanism of Formation of Pa(V) Ion in Hydrous Solutions

open access: yesMolecules, 2019
Due to the enormous threat of protactinium to the environment and human health, its disposal and chemistry have long been important topics in nuclear science.
Jun Ma   +6 more
doaj   +1 more source

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