Results 211 to 220 of about 20,744 (265)
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Dimensionality Control of Electrocatalytic Activity in Perovskite Nickelates
Nano Letters, 2020The dimensionality of the crystal structure plays an important role in the electronic structures of materials. Ruddlesden-Popper perovskite oxides offer an attractive platform for studying this role due to dimensional flexibility. The effects of dimensionality on physical properties in those oxides have been widely reported.
Cong Cao +7 more
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Surface geometry and electrocatalytic activity
Materials Chemistry and Physics, 1989Abstract The theory of electrode reaction was completed some thirty years ago for the hydrogen evolution reaction of reaction type A plus A going to A 2 on pure metals whose surface is composed of single atomic species. However, that for the hydrogen evolution reaction on surfaces composed of two atomic species as well as that for reaction of the ...
S. Motoo, N. Furuya
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Electrochemistry and Electrocatalytic Activity of Cobaloxime Complexes
ChemistrySelect, 2022Abstract Development of clean and renewable energy sources has emerged as one of the major interests due to the environmental issues caused by the fossil fuels . Presently a huge amount of interest has been devoted in developing the cost effective alternative energy sources ...
Subramanian Sowmya, Vijendran Vijaikanth
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Electrocatalytic Oxygen Evolution with an Immobilized TAML Activator
Journal of the American Chemical Society, 2014Iron complexes of tetra-amido macrocyclic ligands are important members of the suite of oxidation catalysts known as TAML activators. TAML activators are known to be fast homogeneous water oxidation (WO) catalysts, producing oxygen in the presence of chemical oxidants, e.g., ceric ammonium nitrate.
Ethan L, Demeter +4 more
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Polyoxometalate-stabilized Pt nanoparticles and their electrocatalytic activities
Physical Chemistry Chemical Physics, 2011The synthesis of long-term stable polyoxometalate (POM)-stabilized Pt nanoparticles (NPs) is described here. By means of controlled bulk electrolysis, the reduced POM anions, SiW(12)O(40)(4-) (or SiW(12)) and H(2)W(12)O(40)(6-) (or H(2)W(12)), respectively, served the dual role of reductant and protecting/stabilizing ligand for the Pt NPs. Transmission
Thomas, Hsu-Yao +3 more
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Size effect of graphene on electrocatalytic activation of oxygen
Chemical Communications, 2011Crystals of graphite nanosheets, achieved via a simple ball milling approach, show a significant size effect in electrocatalytic activation of oxygen.
Deng, Dehui +7 more
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Electrocatalytic activity of DNA on electrodes as an indication of hybridisation
Bioelectrochemistry, 2006Electron transfer between metal electrodes and ferro/ferricyanide is completely suppressed at low ionic concentration. We describe here a new phenomenon related to this reaction: an immobilisation of thiolated single-stranded DNA on gold electrodes retains this activity at low ionic strength up to the level corresponding to the high ionic strength.
Zheng-liang, Zhi +3 more
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Electrocatalytic activity of core/shell magnetic nanocomposite
Analytical Biochemistry, 2014Electrically active magnetic nanocomposites (EAMNCs), Au nanoparticles/self-doped polyaniline@Fe3O4 (AuNPs/SPAN@Fe3O4) with well-defined core/shell structure, were first synthesized by a simple method. The morphology and composition of the as-synthesized AuNPs/SPAN@Fe3O4 nanocomposite have been characterized by transmission electron microscopy (TEM ...
Rong, Tian +3 more
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Chemistry – A European Journal, 2021
AbstractTraditional regulation methods of active sites have successfully optimized the performance of electrocatalysts, but seem unable to achieve further breakthrough in the catalytic activity. Unlike the conventional viewpoint of focusing on single active site, the concept of local microstructure active zone is more comprehensive and new methods to ...
Juanjuan Bian +3 more
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AbstractTraditional regulation methods of active sites have successfully optimized the performance of electrocatalysts, but seem unable to achieve further breakthrough in the catalytic activity. Unlike the conventional viewpoint of focusing on single active site, the concept of local microstructure active zone is more comprehensive and new methods to ...
Juanjuan Bian +3 more
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Origin of Electrocatalytic Activity in Amorphous Nickel–Metalloid Electrodeposits
ACS Applied Materials & Interfaces, 2021In transition metal-based alloys, the nonlinearity of the current at large cathodic potentials reduces the credibility of the linear Tafel slopes for the evaluation of electrocatalytic hydrogen activity. High-precision nonlinear fitting at low current densities describing the kinetics of electrochemical reactions due to charge transfer can overcome ...
Baran Sarac +7 more
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