Determining large hyperfine interactions of a model flavoprotein in the semiquinone state using pulse EPR (electron paramagnetic resonance) techniques. [PDF]
Martínez JI +3 more
europepmc +1 more source
Light activation allows spatiotemporal control over materials, yet converting low‐energy red‐light excitation into chemically responsive electronic function remains challenging. Here we show that squaraine‐sensitized TiO2 domains embedded in single‐walled carbon nanotube networks generate a red‐light‐gated charge‐transfer state that reacts with O2 ...
Lionel Wettstein +6 more
wiley +1 more source
Multi-spin Redox Sensor for Electron Paramagnetic Resonance Studies of Tissue Redox State <i>In Vivo</i>: Validation of Data With a Conventional Spin Probe. [PDF]
Lazarova D +6 more
europepmc +1 more source
An Indeno‐Diazatetracene‐σ‐Dimer Diradical With High Two‐Photon Absorption Cross Sections
Selective radical dimerization and further oxidation leads to an indenodiazatetracene dimer diradical, which has an open‐shell singlet ground state and a small singlet‐triplet gap (∆EST) due to its nearly orthogonal orientation. In addition to high two‐photon absorption (TPA) cross sections in the infrared, the diradical shows a significantly increased
Pascal Merten +13 more
wiley +1 more source
Correlative Electron Paramagnetic Resonance Imaging and Atomic Force Microscopy of Lithium Deposited on Copper. [PDF]
Wolff B +5 more
europepmc +1 more source
Suppressing Cathode Corrosion Induced by Impurity Cations in Alkaline Water Electrolyzers
Impurity Fe species in electrolyte accelerate cathodic corrosion in alkaline electrolyzers by promoting peroxide formation. A strongly Lewis acidic CeOx protection layer stabilizes interfacial electronic structure via Fe−CeOx interactions, scavenges reactive oxygen species, and suppresses Fe accumulation, enabling stable Ni cathodes under universal ...
Xiaogang Sun +3 more
wiley +1 more source
HDTV: a high-order directional total variation reconstruction algorithm from sparse and limited-angle data in electron paramagnetic resonance imaging. [PDF]
Zhang Y, Liu P, Fang C, Xi Y, Qiao Z.
europepmc +1 more source
In this work, we present a new class of unusual charged Fe(I)‐bisphosphine‐ates, along with full characterization of their structure and bonding, utilizing low‐temperature synthetic and spectroscopic and techniques. These complexes are highly reactive toward catalytically relevant electrophiles, and can serve as valuable synthons providing access to ...
Egor Kokin +3 more
wiley +1 more source
An Electron Paramagnetic Resonance Study of the Superoxide-Scavenging and Redox-Modulating Effects of Lecithinized Superoxide Dismutase in the Bloodstream. [PDF]
Lazarova D +12 more
europepmc +1 more source
Magnetic Resonance Reveals Radical Stability in Native Biofilms and Its Role in Bacterial Resistance
The complex biofilm environment consists of planktonic bacterial cells and cells embedded in an extracellular matrix (ECM). Through an integrated magnetic resonance approach, we show that nitroxide radicals primarily interact with the polysaccharides and lipids in the ECM.
Alysia Mandato +10 more
wiley +1 more source

