Electron transfer reaction and demetalation of phthalocyanines
An electron-transfer reaction takes place in the ground state between phthalocyanines (as electron-donors) and pyrylium cations (as electron-acceptors) in polar solvents, reaction which leads to the phthalocyanine radical-cations as evidenced by its ...
Jean Kossanyi, Driss Chahraoui
doaj +1 more source
Concerted proton-electron transfer reactions in the Marcus inverted region
Protons venture into the inverted region One of the most counterintuitive features of electron transfer kinetics is the inverted region. As Marcus theory predicts and experiments have borne out, electron transfer slows down once the driving force for it ...
Giovanny A. Parada +7 more
semanticscholar +1 more source
Does Koopmans’ Paradigm for 1-Electron Oxidation Always Hold? Breakdown of IP/E\u3csub\u3eox\u3c/sub\u3e Relationship for \u3cem\u3ep\u3c/em\u3e-Hydroquinone Ethers and the Role of Methoxy Group Rotation [PDF]
Koopmans’ paradigm states that electron loss occurs from HOMO, thus forming the basis for the observed linear relationships between HOMO/IP, HOMO/Eox, and IP/Eox.
Boddeda, Anitha +3 more
core +1 more source
A tri‐culture of iPSC‐derived neurons, astrocytes, and microglia treated with ferroptosis inducers as an Induced ferroptosis model was characterized by scRNA‐seq, cell survival, and cytokine release assays. This analysis revealed diverse microglial transcriptomic changes, indicating that the system captures key aspects of the complex cellular ...
Hongmei Lisa Li +6 more
wiley +1 more source
In the present study the quantum molecular dynamics method was applied to an energy transfer problem to an electron during ionic surface collision process in order to elucidate how energy of ionic collision transfers to the emitted electrons.
Masahiko SHIBAHARA +2 more
doaj +1 more source
Understanding the nature of mean-field semiclassical light-matter dynamics: An investigation of energy transfer, electron-electron correlations, external driving, and long-time detailed balance [PDF]
Tao E. Li +3 more
openalex +1 more source
Rapid electron transfer by the carbon matrix in natural pyrogenic carbon
Surface functional groups constitute major electroactive components in pyrogenic carbon. However, the electrochemical properties of pyrogenic carbon matrices and the kinetic preference of functional groups or carbon matrices for electron transfer remain ...
Tianran Sun +6 more
semanticscholar +1 more source
Electron Transfer Reaction Through an Adsorbed Layer [PDF]
We consider electron transfer from a redox to an electrode through and adsorbed intermediate. The formalism is developed to cover all regimes of coverage factor, from lone adsorbate to monolayer regime. The randomness in the distribution of adsorbates is
Cruz, A. V. B. +2 more
core
Self-assembly and electron-beam-induced direct etching of suspended graphene nanostructures
We report on suspended single-layer graphene deposition by a transfer-printing approach based on polydimethylsiloxane stamps. The transfer printing method allows the exfoliation of graphite flakes from a bulk graphite sample and their residue-free ...
Fabio Beltram +7 more
core +1 more source
BMI‐1 modulation and trafficking during M phase in diffuse intrinsic pontine glioma
The schematic illustrates BMI‐1 phosphorylation during M phase, which triggers its translocation from the nucleus to the cytoplasm. In cycling cells, BMI‐1 functions within the PRC1 complex to mediate H2A K119 monoubiquitination. Following PTC596‐induced M phase arrest, phosphorylated BMI‐1 dissociates from PRC1 and is exported to the cytoplasm via its
Banlanjo Umaru +6 more
wiley +1 more source

