Results 241 to 250 of about 482,591 (311)

π‐Enlargement in Porphyrin Macrocycles at Interfaces

open access: yesAngewandte Chemie, EarlyView.
On‐surface synthesis of a 20‐π free‐base expanded porphyrin, by depositing onto a hot Ag(111) substrate an 18‐π free‐base precursor equipped with ‐CF3 functional groups ABSTRACT Porphyrins are essential heteroatomic macrocycles, fundamental to both biological systems and advanced technology.
Ana Barragán   +11 more
wiley   +1 more source

Cost Avoidance Associated with Aspirin De-Prescribing Among Patients Receiving Warfarin. [PDF]

open access: yesTH Open
Falvello V   +12 more
europepmc   +1 more source

Mixed‐Functionalized Acylgermanes Result in Wavelength‐Controlled Fragmentation

open access: yesAngewandte Chemie, EarlyView.
Selective radical generation from PEG‐acylgermanes is achieved by controlling the used wavelength. Distinct aryl‐carbonyl units undergo wavelength‐dependent α‐cleavage, producing radicals with different reactivities. UV/Vis, TD‐DFT, and photo‐CIDNP spectroscopy confirm that small adjustments in light input directly dictate radical identity and ...
André Culum   +6 more
wiley   +1 more source

Design Rules for Controlling Connectivity, Topology, and Sorting Using Hydrogen‐Bonded Pairs and Aromatic Components in Palladium(II)‐Based Interlocked and Foldameric Systems

open access: yesAngewandte Chemie, EarlyView.
We have established a set of design rules which combine Pd(II) metal coordination, complementary geometries, complementary interligand hydrogen bonding and π─π interactions for predictable self‐assembly of Pd(II)‐based species such as metallo‐foldamers, cyclic species a metallo‐interlocked clippane. The species persist in a combinatorial mixture due to
Jess L. Algar   +2 more
wiley   +1 more source

One‐Step Radical‐Intensified Selective Etching (RISE) Strategy for High‐Yield Synthesis of Monolayer MXene with Tailored Nanoholes

open access: yesAngewandte Chemie, EarlyView.
Radical‐intensified selective etching (RISE) delivers monolayer MXenes with >80% yield in just 3 h etching process. Controlled ·OH dosage enables one‐step access to holey MXenes with abundant nanopores or defect‐lean flakes. This mild, safe strategy couple ultrafast kinetics with structural tunability, advancing precision design of MXene architectures.
Chenxu Liu   +8 more
wiley   +1 more source

Patient perspectives on cost and quality measures in value-based cancer care. [PDF]

open access: yesHealth Aff Sch
Balch A   +7 more
europepmc   +1 more source

Home - About - Disclaimer - Privacy