Results 271 to 280 of about 317,288 (335)

Exploring Indium Teflates: From Neutral In(OTeF5)3(THF)3 to Anionic Complexes [In(OTeF5)4(THF)2]– and [In(OTeF5)6]3–

open access: yesChemistryEurope, EarlyView.
The study examines the coordination chemistry of indium teflate complexes, showing the progression from [In(OTeF5)3(THF)3] to the anionic species [In(OTeF5)4(THF)2]– and [In(OTeF5)6]3–. Systematic ligand substitution and anion formation reveal increasing teflate coordination, highlighting structural evolution, Lewis acidity modulation, and ...
Djamila Azrou   +7 more
wiley   +1 more source

NH‐Sulfilimine Synthesis Catalyzed by Nonheme Iron(II) Complex

open access: yesChemistryEurope, EarlyView.
Sulfilimines are emerging as valuable functional group in modern medicinal chemistry. Yet, their catalytic preparation is underexplored compared to sulfoximines. Here, the iron‐catalyzed synthesis of 14 examples of unprotected sulfilimines in good yields, under aerobic atmosphere and at room temperature, is described.
Léa Tesson   +2 more
wiley   +1 more source

Dipolar Molecular Motor Candidates with Planar Chirality

open access: yesChemistry – A European Journal, EarlyView.
Two prototypes of molecular motors with simultaneous implementation of planar chirality and a permanent dipole have been designed and synthesized in 7 steps with overall yields of 2.8 to 5.5%. Abstract Two molecular motor candidates built around ruthenium(II) centers featuring both planar chirality and a permanent dipole have been synthesized in seven ...
Thomas A. Hector   +5 more
wiley   +1 more source

Construction of Phospholipid‐Like Vesicles by Aqueous Aminolysis of Acyl Thioesters With Diamino Acids

open access: yesChemistry – A European Journal, EarlyView.
Membrane‐forming phospholipids are produced in cells via enzymatic diacylation. Here, we show that direct aminolysis of acyl thioesters with diamino acids in aqueous environments enables the synthesis of diacylated amino acids (DAAAs), which spontaneously self‐assemble into robust phospholipid‐like vesicles across a broad range of pH and temperature ...
Federica A. Souto‐Trinei   +2 more
wiley   +1 more source

Experimentation of Electrospray Methodology with Carbon Nanotubes

open access: gold, 2020
Shannon K. O’Connor   +4 more
openalex   +1 more source

Copper(II), a Peculiar Metal Ion for Complexation with Monensin A Ionophore

open access: yesChemistry – A European Journal, EarlyView.
Copper(II) forms three chiral and EPR‐active complexes with monensinate A in methanol. Beside the bis [CuL2] and mono [CuL]+ species, the new dinuclear construct [Cu2L]3+ exhibits an [ML]+‐type and a metal salt‐type copper(II) centers weakly bound to each other through counter ion(s) and thus, being magnetically independent.
Máté Levente Kis   +7 more
wiley   +1 more source

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