Results 161 to 170 of about 195,229 (259)

H2O2 Activation and Alkane Oxidation by Copper Complexes With R‐dpa N3‐Tridentate Ligands: The Complex‐Based Dicopper Active Species as a Key Feature in the Efficient Alkane Oxidation

open access: yesChemistry – A European Journal, EarlyView.
Two reaction pathways, Paths 1 and 2, are involved in H2O2 activation by Cu complexes with N3‐tridentate ligands, depending on the ease of bridging structure formation. In Path 1, hydroxy radical (HO•) is formed from a hydroperoxo Cu(II) intermediate. In Path 2, a relevant complex‐based μ‐O• bridged Cu(II)2 active species is formed from a bis‐μ‐oxo Cu ...
Kyosuke Fujikawa   +5 more
wiley   +1 more source

Phosphorescent Iridium Hydrazinonicotinic Acid (HYNIC) Complexes That Bind to Prostate Specific Membrane Antigen: Potential Photodynamic Therapy of Prostate Cancer

open access: yesChemistry – A European Journal, EarlyView.
A phosphorescent iridium(III) complex has been prepared with a 6‐hydrazinonicotinic acid (HYNIC) ligand tethered to a lysine‐ureido‐glutamatic acid pharmacophore, which binds to an enzyme, called prostate‐specific membrane antigen (PSMA), which is overexpressed in prostate cancer.
La'El Kimchi   +6 more
wiley   +1 more source

Total Syntheses of Agelamadin F and (±)‐Tauroacidin A, Enabled by NaClO2‐Mediated Coupling Reactions of Oroidin and Amines

open access: yesChemistry – A European Journal, EarlyView.
Total syntheses of agelamadin F and (±)‐tauroacidin A were achieved by sodium chlorite (NaClO2)‐mediated oxidative C─N coupling. Nine C15–N–amino acid‐substituted oroidin derivatives were successfully prepared to demonstrate the applicability and versatility of this oxidative coupling reaction.
Ryosuke Hirozumi   +3 more
wiley   +1 more source

Bioinspired Design and Synthesis of Polyphenolic Star‐Like and Hyperbranched Polyester Models

open access: yesChemistry – A European Journal, EarlyView.
Gallotannin‐inspired star‐like and hyperbranched aromatic polyesters were synthesized from D‐glucose and ABn‐type phenolic acid monomers, such as protocatechuic acid. This bioinspired approach afforded polyphenolic polymeric nanoparticles able to encapsulate hydrophobic dyes, opening new perspectives for biobased encapsulation and delivery systems ...
Guanfei Shen   +4 more
wiley   +1 more source

Prism[5]MaxQ: A Sulfated Prism[5]Arene and Its Molecular Recognition Properties Toward a Panel of Quaternary Ammonium Guests

open access: yesChemistry – A European Journal, EarlyView.
We report the synthesis and characterization of a sulfated prism[5]arene host (Prism[5]MaxQ). Prism[5]MaxQ displays ultrahigh binding affinity (Ka up to 1012 M−1) toward hydrophobic (di)cations in phosphate‐buffered saline (PBS). The work positions Prism[5]MaxQ as a new member of the family of ultrahigh‐affinity hosts poised for use as a sequestrant in
Emmanuel A. Bazan‐Bergamino   +1 more
wiley   +1 more source

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