Results 131 to 140 of about 41,102 (313)

Redox Complexity in Sodium Manganese Hexacyanomanganate and Its Influence on Sodium‐Ion Storage Performance

open access: yesAdvanced Energy Materials, EarlyView.
The role of each Mn site in the Na3‐xMn[Mn(CN)6]·zH2O compounds’ redox activity was investigated using a combined experimental–computational approach, which shows that only the low‐spin Mn‐C site undergoes redox changes (Mn1+ to Mn4+), while high‐spin Mn‐N remains unchanged. The study confirms the presence of the Mn1+ intermediate and newly reveals its
Zhenying Li   +11 more
wiley   +1 more source

Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

open access: yesAngewandte Chemie, EarlyView.
H2O2‐directed solvate engineering reorganizes ∞[4HP] (4‐hydroxypyridine) chains from a crossed arrangement into a nearly parallel packing through strengthened hydrogen‐bonding interactions. The resulting peroxide‐containing crystal, 4HP·H2O2, exhibits a solar‐blind UV cutoff edge (278 nm) and giant birefringence (0.609 @ 546 nm). This work demonstrates
Yang Li, Congcong Jin, Kang Min Ok
wiley   +2 more sources

Organic Photoelectrochemical Cells Beyond Performance: Interface and Catalyst Engineering for Durability

open access: yesAdvanced Energy Materials, EarlyView.
Organic photoelectrochemical cells based on π‐conjugated semiconductors offer a versatile platform for solar fuel generation. This review outlines operating principles, device architectures, and key metrics, and highlights advances in p‐ and n‐type photoelectrodes, interfacial engineering, and catalyst integration.
Jaehyeong Kim   +8 more
wiley   +1 more source

Ketal Protection of Glycerol for Selective Electrosynthesis of Glyceric Acid in Highly Alkaline Media

open access: yesAngewandte Chemie, EarlyView.
Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang   +6 more
wiley   +2 more sources

Built‐In Electric Field Regulated Electron Transport Channels of FeP Supported Os for Ampere‐Level Seawater Electrolysis

open access: yesAdvanced Energy Materials, EarlyView.
This work presents an Os/FeP heterostructure catalyst with EMSI and successfully utilizes the BEF to further modulate electron transfer through Os‐P‐Fe channels, proving an effective approach of developing low‐cost electrocatalysts with remarkable HER activity in ampere‐level seawater electrolysis. ABSTRACT Developing cost‐effective and robust hydrogen
Qing Liu   +13 more
wiley   +1 more source

Tunnel‐Framework Interphase Driving Rapid Zn2+ Diffusion for Long‐Life Zn Metal Anodes

open access: yesAdvanced Energy Materials, EarlyView.
The construction of an artificial interphase with 3D tunnel‐framework effectively suppresses interfacial water‐induced side reactions and dendrite growth. ABSTRACT Aqueous zinc‐ion batteries (AZIBs) are presently attracting considerable interest for large‐scale energy storage owing to their low cost and high safety.
Kunpeng Gao   +3 more
wiley   +1 more source

Quantitative Photo‐Reforming of Biomass to CO Spurred by In Situ Protonation of Carbon Dioxide Radical Anions

open access: yesAngewandte Chemie, EarlyView.
A “two‐in‐one” photoreduction strategy enabled by electron‐rich yolk Cd species both remote from and adjacent to sulfur vacancies is delivered to be ultraselective for the reduction of O2 and •CO2− in situ formed on the shell Bi2S3 composition (hole) by water oxidation and oxidative C–C cleavage of various biomass organic acids, furnishing CO with > 99%
Tengyu Liu   +5 more
wiley   +2 more sources

Data‐Driven High‐Throughput Volume Fraction Estimation From X‐Ray Diffraction Patterns

open access: yesAdvanced Intelligent Discovery, EarlyView.
Long exposure times and the need for manual evaluation limit the use of X‐ray diffraction in high‐throughput applications. This study presents a data‐driven approach addressing both issues. HiVE (a method for High‐throughput Volume fraction Estimation) performs composition estimation for high‐noise XRD patterns produced using polychromatic emission ...
Hawo H. Höfer   +6 more
wiley   +1 more source

Effect of physical activity and 217-Hz extremely low frequency electromagnetic field on rat locomotor activity

open access: yesFiyz̤, 2017
Background: Nowadays the widespread use of cell phones has increased concerns about the biological effects of electromagnetic fields on human body. The purpose of the present study was to examine the role of physical activity in moderating the effects of
Rasol Zeidabadi   +3 more
doaj  

Ultrasonic Rainbow: A Meta‐Transducer for Frequency‐Selective Elastic Wave Control via Dithering‐Based Wavenumber Tuning

open access: yesAdvanced Intelligent Systems, EarlyView.
A piezoelectric meta‐transducer generates an ultrasonic rainbow, steering guided elastic waves to different angles according to frequency. A dithering‐based binary electrode design enables a closer realization of the target wavenumber filter, improving directional purity and suppressing unwanted lobes. Numerical and experimental validation demonstrates
Masoud Mohammadgholiha   +5 more
wiley   +1 more source

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