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Orientation disorder in ammonium elpasolites
Journal of Fluorine Chemistry, 2003Abstract Crystal structures of the known (NH4)3AlF6(I) and (NH4)3FeF6(III) and new (NH4)3TiOF5(II) elpasolites were refined by localizing anions (F−, O2−) in four acceptable positions of the cubic system Fm3m (Z=4) with a=8.9401(3), 9.1104(3), 9.110(1) A, respectively. According to the refinement data and a rather large entropy change due to fluorine
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