Results 131 to 140 of about 5,652,554 (195)

Perfluorocubane as a σ* orbital-based electron acceptor beyond classical electron-transfer models. [PDF]

open access: yesNat Commun
Akiyama M   +10 more
europepmc   +1 more source

Molecular Basis of c‑MET Inhibition by Approved Small Molecule Drugs: A Structural Perspective. [PDF]

open access: yesACS Med Chem Lett
Russell IC   +7 more
europepmc   +1 more source

On‐Surface Friedel–Crafts Alkylation Through a Stabilized Intermediate Complex

open access: yesAngewandte Chemie International Edition, EarlyView.
On‐surface Friedel–Crafts alkylation is demonstrated on Ag(111) at the single‐molecule level. STM, XPS, and DFT calculations uncover the reaction mechanism and explain the stabilization of the key intermediate, providing insight into noble‐metal‐surface‐mediated Csp3${\rm C}_{sp^{3}}$─Csp2${\rm C}_{sp^{2}}$ coupling. ABSTRACT The incorporation of sp3${\
Paul Schweer   +5 more
wiley   +1 more source

Transformative Masked Ortho‐Quinone Chemistry: From Direct Guaiacol Activation to Lignin‐Based Adhesives

open access: yesAngewandte Chemie International Edition, EarlyView.
Renewable guaiacols are rapidly oxidized by phenyliodine(III)diacetate to masked ortho‐quinones, giving a new class of monomers that undergo selective Michael‐type polyaddition with multithiols to from thiol‐guaiacol connectivity‐bearing polymers. The activation applies to discrete monomers and directly to lignin, enabling two‐component adhesives that ...
Dominik P. Hoch   +7 more
wiley   +1 more source

Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective. [PDF]

open access: yesAngew Chem Int Ed Engl
Xie E   +11 more
europepmc   +1 more source

Bistable Switching of π‐Conjugation in a Dithienylethene‐Bridged Luminescent Trityl Diradicaloid

open access: yesAngewandte Chemie International Edition, EarlyView.
Photoswitches that affect π‐conjugation offer a powerful strategy for external manipulation of luminescent diradicals. Dithienylethene‐linked persistent trityl diradicaloids, DTE‐TTM2 and F6‐DTE‐TTM2, exhibit bistable switching of their optical, electrochemical and magnetic properties.
Xingmao Chang   +11 more
wiley   +1 more source

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