Results 111 to 120 of about 86,276 (266)

Chiral Crystal Growth under Grinding

, 2008
To study the establishment of homochirality observed in the crystal growth experiment of chiral molecules from a solution under grinding, we extend the lattice gas model of crystal growth as follows. A lattice site can be occupied by a chiral molecule in
Becker R., Brandenburg A., Frank F. C., Japp F. R., Kipping F. S., Kondepudi D. K., Mauksch M., Noorduin W. L., Noorduin W. L., Ostwald W., Pasteur L., Plasson R., Saito Y., Saito Y., Saito Y., Saito Y., Sato I., Shibata R., Soai K., Uwaha M., Uwaha M., Viedma C.   +21 more
core   +1 more source

Pharmacokinetics and pharmacodynamics of intravenous and oral (S)‐ketamine: Investigating metabolite contribution to subjective effects

British Journal of Clinical Pharmacology, EarlyView.
Aims Oral administration of (S)‐ketamine for treatment‐resistant depression (TRD), as alternative to the registered intranasal or off‐label intravenous administrations, has high potential. However, it is characterized by an extensive first‐pass metabolism, resulting in low (S)‐ketamine exposure and high levels of active metabolites, including (S ...
Marije E. Otto, Gabriël E. Jacobs, Joost C. van Mechelen, Laura G. J. M. Borghans, Johan G. C. van Hasselt, Linda B. S. Aulin   +5 more
wiley   +1 more source

Ratio of l-(+)- and d-(−)-Lactic Acids Produced by Enterococcus faecalis Changes Depending on the Culture pH

Microbiology Research
Enterococcus faecalis (E. faecalis) has been associated with the specific production of l-(+)-lactic acid. However, in this study, d-(−)-lactic acid production by E. faecalis was observed under specific pH conditions. E.
Kanako Matsunaga, Yasuhiko Komatsu
doaj   +1 more source

Influence of Zn2+ and Oxygen Supply on Malic Acid Production and Growth of Aspergillus oryzae

Biotechnology and Bioengineering, EarlyView.
ABSTRACT Malic acid is a valuable platform chemical traditionally derived from fossil‐based resources. Microbial cultivation with Aspergillus oryzae offers a sustainable alternative based on renewable feedstocks. In this study, a well‐established minimal medium for malic acid production, commonly used in previous research to ensure reproducibility, was
Lukas Hartmann, Anke Neumann, Dirk Holtmann, Katrin Ochsenreither   +3 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Guidance of EFSA on risk assessments for active substances of plant protection products that have stereoisomers as components or impurities and for transformation products of active substances that may have stereoisomers

EFSA Journal, 2019
In response to the request of the European Commission to EFSA, this document provides guidance on the information necessary to perform the risk assessment of plant protection active substances that contain stereoisomers in their composition as active ...
European Food Safety Authority (EFSA), László Bura, Anja Friel, José Oriol Magrans, Juan Manuel Parra‐Morte, Csaba Szentes   +5 more
doaj   +1 more source

Decoupling Redox Potentials and Excited State Energies in Substituted Chromium(III) Chromophores

Chemistry – A European Journal, EarlyView.
Redox and excited state properties of organic and precious metal CT photocatalysts are strongly entangled. In contrast, redox potentials of polypyridine chromium(III) complexes, that feature purely metal‐centered SF states, are selectively tuned by incremental substituent effects of the CF3 group, while excited state energies and lifetimes remain ...
Steven Sittel, Dimitri Zorn, Alexandra König, Jonas Marcel Grenz, Christoph Förster, Robert Naumann, Katja Heinze   +6 more
wiley   +1 more source

Porphyrin‐Geländer–Helical Conjugated Banister Type Porphyrin Dyads

Chemistry – A European Journal, EarlyView.
Porphyrin arrays go chiral–A porphyrin Geländer macrocycle represents the intriguing prototype architecture of helically chiral butadiyne‐linked porphyrin arrays. This study combines synthetic, spectroscopic, and computational methods to shed light on its structure, chiroptical properties, and tunability, highlighting its promise for advancing ...
Joël F. Keller, Adriano D'Addio, Marcel Mayor   +2 more
wiley   +1 more source

Time-Resolved Circular Dichroism in Molecules: Experimental and Theoretical Advances

Molecules
Following changes in chirality can give access to relevant information on the function or reactivity of molecular systems. Time-resolved circular dichroism (TRCD) spectroscopy proves to be a valid tool to achieve this goal.
Marta Monti, Leonardo Biancorosso, Emanuele Coccia   +2 more
doaj   +1 more source

Tuning the Twist by Molecular Design: A New Strategy for Hexabenzocoronene‐Containing Helical Twistacene

Chemistry – A European Journal, EarlyView.
An efficient Scholl–based strategy enables precise control of the C–C bond to access the first hexabenzocoronene–containing helical twistacene (NG2). The resulting nanographene shows pronounced helical distortion, high stability, enhanced solubility, and promising redox and optoelectronic properties.
Juan P. Mora‐Fuentes, Daniel Villar‐Castro, J. Francisco Barbosa‐de‐Bessa, Daniel Aranda, Frank Hampel, Dolores Pérez, M. Eugenia Pérez‐Ojeda, Diego Peña, Andreas Hirsch   +8 more
wiley   +1 more source