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Novel dinitromethyl-featured polynitro energetic salts
Dalton Transactions, 2016An unique and facile method was developed to synthesize a new class of energetic salts based on 2-amino-1,1,5,5-tetranitro-4-oxo-3-aza-pentene (ATNP) anion in one-pot reaction. These salts exhibited promising detonation performances (detonation pressure: 28.6 to 34.3 GPa; detonation velocity: 8037 to 8674 m s−1) which were comparable to those of RDX.
Ying, Li +4 more
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A π-stacking highly stable insensitive energetic inner salt and its insensitive energetic salts
CrystEngComm, 2023The energetic inner salts of π–π stacking and their energetic ionic salts show high thermal stability (Td ≥ 238 °C), insensitivity (FS ≥ 360 N, IS ≥ 40 J), and good detonation performance (D ≥ 7757 m s−1, P ≥ 24.1 GPa).
Jinhao Zhang +8 more
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1,2,4‐Triazolium‐Cation‐Based Energetic Salts
Chemistry – A European Journal, 2008Abstract3,4,5‐Triamino‐1,2,4‐triazole (guanazine, 1) can be readily methylated with methyl iodide yielding methylguanazinium iodide (2). Salts containing the novel methylguanazinium cation with energetic anions were synthesised by metathesis reactions with silver azide (3), silver nitrate (4), silver perchlorate (5), sodium 5,5′‐azotetrazolate (6 ...
Chaza, Darwich +2 more
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Computational Characterization of Energetic Salts
The Journal of Physical Chemistry C, 2007Using the experimental (or calculated) values for densities, a combination of theoretical and empirical calculations are powerful tools in predicting heats of formation of energetic salts. The heats of formation of cations and anions and lattice energies were calculated separately based on Born−Haber energy cycles.
Haixiang Gao +3 more
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ACS Applied Materials and Interfaces
The field of high energy density materials faces a long-standing challenge to achieve an optimum balance between energy and stability. While energetic salt formation via a combination of oxygen- and nitrogen-rich anions (providing energy) with nitrogen ...
Prachi Bhatia +2 more
semanticscholar +1 more source
The field of high energy density materials faces a long-standing challenge to achieve an optimum balance between energy and stability. While energetic salt formation via a combination of oxygen- and nitrogen-rich anions (providing energy) with nitrogen ...
Prachi Bhatia +2 more
semanticscholar +1 more source
Dalton Transactions
The development of energetic materials is still facing challenges due to the inherent contradiction between energy and sensitivity. Two new nitrogen-rich energetic salts of 3,4,5-1H-trinitropyrazole (HTNP) were synthesized.
Chenchen Lin +5 more
semanticscholar +1 more source
The development of energetic materials is still facing challenges due to the inherent contradiction between energy and sensitivity. Two new nitrogen-rich energetic salts of 3,4,5-1H-trinitropyrazole (HTNP) were synthesized.
Chenchen Lin +5 more
semanticscholar +1 more source
Energetic Silver Salts with 5‐Aminotetrazole Ligands
Chemistry – A European Journal, 2009AbstractMethylation of 5‐amino‐1H‐tetrazole (1) gives 1‐methyl‐5‐amino‐1H‐tetrazole (2) and 2‐methyl‐5‐amino‐1H‐tetrazole (3). A new family of energetic silver complexes based on ligands 1, 2 and 3 with perchlorate and nitrate anions (10–15) were synthesized and characterized by using IR, Raman, and NMR (1H, 13C, 14N, and 35Cl NMR) spectroscopy ...
Konstantin, Karaghiosoff +2 more
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Tetraanionic Nitrogen‐Rich Tetrazole‐Based Energetic Salts
Chemistry – An Asian Journal, 2013Abstract1,1,3,3‐Tetra(1H‐tetrazol‐5‐yl)propane‐based energetic salts were synthesized in a simple and straightforward manner. The structures of these new salts were determined by 1H and 13C NMR spectroscopy, IR spectroscopy, MS, and elemental analysis.
Dharavath, Srinivas +3 more
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Energetic Nitrogen‐Rich Salts and Ionic Liquids
ChemInform, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Rajendra P, Singh +3 more
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Syntheses of Energetic cyclo‐Pentazolate Salts
Chemistry – An Asian Journal, 2019AbstractThree energetic salts of cyclo‐N5− were synthesized via a metathesis reaction of barium pentazolate and sulfates which was driven by the precipitation of BaSO4. All the energetic cyclo‐N5− salts were characterized by single‐crystal X‐ray diffraction, infrared (IR), 1H and 13C multinuclear NMR spectroscopies, thermal analysis (TGA and DSC), and ...
Lili Tian +4 more
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