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Midway between Energetic Molecular Crystals and High-Density Energetic Salts: Crystal Engineering with Hydrogen Bonded Chains of Polynitro Bipyrazoles

, 2020
A new strategy for supramolecular synthesis of energetic salts is reported. It is still a challenge to address packing patterns and crystal morphologies of such materials due to the lack of reliabl...
I. Gospodinov   +4 more
semanticscholar   +1 more source

4‐Nitramino‐3,5‐dinitropyrazole‐Based Energetic Salts

Chemistry – A European Journal, 2011
Abstract4‐Nitramino‐3,5‐dinitropyrazole was prepared and stabilized through the formation of its ammonium salt. With selected cations, 14 nitrogen‐rich energetic salts were synthesized in high yield by metathesis reactions. These salts were fully characterized by 1H, 13C NMR, and IR spectroscopy and elemental analysis.
Yanqiang, Zhang   +2 more
openaire   +2 more sources

Energetic Quaternary Salts Containing Bi(1,2,4-triazoles)

Inorganic Chemistry, 2005
New energetic salts (2, 3, 9, 10, and 11) were synthesized via the protonation of 4,4'-bi(1,2,4-triazole) or N-4-(1,2,4-triazole)-N-3-(4-methyl-1,2,4-triazole)amine with nitric acid or perchloric acid or 5-nitro-tetrazole. The structures of 4,4'-bi(1,2,4-triazolium) nitrate (2), N,N-dimethyl-N'-(5-methyl-tetrazole)methanimidamide (8), and N-4-(1,2,4 ...
Hong, Xue   +2 more
openaire   +2 more sources

Nitrogen-rich nitroguanidyl-functionalized tetrazolate energetic salts

Chemical Communications, 2009
A series of nitrogen-rich nitroguanidyl-functionalized tetrazolate salts paired with guanidinium-derivatized and heterocycle-based cations were synthesized and most exhibit better thermal stability, higher density and more positive heat of formation than their tetrazolate analogues.
Ruihu, Wang   +3 more
openaire   +2 more sources

New pyrazole energetic materials and their energetic salts: combining the dinitromethyl group with nitropyrazole.

Dalton Transactions, 2020
In this work, a series of pyrazole-derived energetic compounds were successfully synthesized. These energetic compounds were fully characterized by NMR spectroscopy, IR spectroscopy, and elemental analysis. The structures of compounds 5, 6, 7 and 7a were
Caijin Lei, Hongwei Yang, G. Cheng
semanticscholar   +1 more source

A Review of Catalytic Effects of Energetic Ionic Salts on Combustion of Solid Propellants

Propellants, explosives, pyrotechnics
This article presents a comprehensive review of the research advancements in catalysts used within solid propellants, with a particular focus on energetic ionic salt catalysts.
Fan Zhang   +3 more
semanticscholar   +1 more source

Energetic salts prepared from phenolate derivatives

New J. Chem., 2014
Energetic salts with 1 : 1, 2 : 1, and 3 : 1 charge ratios (cation : anion) based on various nitrogen-rich cations and phenolate anions have been synthesized by a straightforward and simple method.
Dharavath Srinivas   +2 more
openaire   +1 more source

Modification of crystalline energetic salts through polymorphic transition: enhanced crystal density and energy performance

, 2020
Crystal engineering plays a vital role in the development of energetic materials. In this study, the polymorphs of 3-nitramino-4-(4,5-diamino-1,2,4-triazole-3-yl)-furazan (3) were investigated and confirmed by single crystal X-ray diffraction.
Yang Liu, Yuan-gang Xu, Qi Sun, Ming Lu
semanticscholar   +1 more source

Energetic Salts of Symmetrical Dimethylhydrazine (SDMH)

European Journal of Inorganic Chemistry, 2011
AbstractN,N′‐Dimethylhydrazine and several of its salts with energetic anions were synthesized and fully characterized by elemental analysis, DSC, mass spectrometry, multinuclear NMR (1H, 13C, and 15N) spectroscopy, and vibrational (Raman, IR) spectroscopy.
Carles Miró Sabaté, Henri Delalu
openaire   +1 more source

Guanidinium Dicyanamide-Based Nitrogen-Rich Energetic Salts as Additives of Hypergolic Ionic Liquids

, 2020
In this paper, four kinds of guanidinium dicyanamide-based energetic salts were prepared and investigated as energetic additives to hypergolic ionic liquid 1-ethyl-3-methyl imidazolium dicyanamide ...
Changgeng Sun, Shaokun Tang
semanticscholar   +1 more source

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