Results 31 to 40 of about 21,587 (210)

GDP-Mannose 3,5-Epimerase: A View on Structure, Mechanism, and Industrial Potential

open access: yesFrontiers in Molecular Biosciences, 2022
GDP-mannose 3,5-epimerase (GM35E, GME) belongs to the short-chain dehydrogenase/reductase (SDR) protein superfamily and catalyses the conversion of GDP-d-mannose towards GDP-l-galactose.
Koen Beerens   +2 more
doaj   +1 more source

Amino acid racemization dating of marine shells: a mound of possibilities [PDF]

open access: yes, 2007
Shell middens are one of the most important and widespread indicators for human exploitation of marine resources and occupation of coastal environments. Establishing an accurate and reliable chronology for these deposits has fundamental implications for ...
Bailey, Geoffrey N.   +5 more
core   +4 more sources

Photocatalyzed Ring Expansion of α-Ketosulfonylaziridines: Ready Access to δ-Sultams. [PDF]

open access: yesAngew Chem Int Ed Engl
A novel radical–polar crossover (RPC) photoredox‐catalyzed reaction for the synthesis of δ‐sultams from N‐sulfonyl α‐ketoaziridines through a controlled ring opening–expansion process is presented. This method allows the easy access to sultams with an unprecedented substitution pattern in up to 85% yield and 2:1 d.r., and highlights the potential of ...
Mastandrea MM   +7 more
europepmc   +3 more sources

Stereoselective Epimerizations of Glycosyl Thiols

open access: yesOrganic Letters, 2017
Glycosyl thiols are widely used in stereoselective S-glycoside synthesis. Their epimerization from 1,2-trans to 1,2-cis thiols (e.g., equatorial to axial epimerization in thioglucopyranose) was attained using TiCl4, while SnCl4 promoted their axial-to-equatorial epimerization.
Lisa M. Doyle   +5 more
openaire   +3 more sources

Investigation of the Ergopeptide Epimerization Process

open access: yesComputation, 2014
Ergopeptides, like ergocornine and a-ergocryptine, exist in an S- and in an R-configuration. Kinetic experiments imply that certain configurations are preferred depending on the solvent. The experimental methods are explained in this article. Furthermore,
Karsten Andrae   +6 more
doaj   +1 more source

Ostracode-based aminostratigraphy and aminochronology of a tufa system in central Spain [PDF]

open access: yes, 2005
In the Priego area, central Spain, extensive tufa deposits are located in three small tributaries located at the head of the 1000 kmlong Tagus River. The deposits are originated after karst-origin running waters emerged from the confines of the canyons ...
Andrews   +46 more
core   +2 more sources

Advances in the chemistry, pharmacological diversity, and metabolism of 20(R)-ginseng saponins

open access: yesJournal of Ginseng Research, 2020
Ginseng has been used as a popular herbal medicine in East Asia for at least two millennia. However, 20(R)-ginseng saponins, one class of important rare ginsenosides, are rare in natural products. 20(R)-ginseng saponins are generally prepared by chemical
Chaoming Wang   +6 more
doaj   +1 more source

Bacterial epimerization as a route for deoxynivalenol detoxification: the influence of growth and environmental conditions.

open access: yesFrontiers in Microbiology, 2016
Deoxynivalenol (DON) is a toxic secondary metabolite produced by several Fusarium species that infest wheat and corn. Food and feed contaminated with DON pose a health risk to both humans and livestock and form a major barrier for international trade ...
Jian Wei eHe   +6 more
doaj   +1 more source

Microbiota and bile acid profiles in retinoic acid-primed mice that exhibit accelerated liver regeneration. [PDF]

open access: yes, 2015
Background & aimsAll-trans Retinoic acid (RA) regulates hepatic lipid and bile acid homeostasis. Similar to bile acid (BA), RA accelerates partial hepatectomy (PHx)-induced liver regeneration.
Hu, Ying   +2 more
core   +2 more sources

Synthesis of rare sugars via epimerization catalyzed by tin-organic frameworks

open access: yesCurrent Research in Green and Sustainable Chemistry
Epimerization of readily available monosaccharides presents an atom-efficient approach to expand the portfolio of rare monosaccharides. Here, we report tin-organic frameworks (Sn-OF) as a highly selective catalyst for synthesis of rare monosaccharides ...
Valérie Toussaint   +3 more
doaj   +1 more source

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