Structure-based prediction and identification of 4-epimerization activity of phosphate sugars in class II aldolases [PDF]
Scientific Reports, 2017 Sugar 4-epimerization reactions are important for the production of rare sugars and their derivatives, which have various potential industrial applications.
Seon-Hwa Lee +6 more
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Synthesis of rare sugars via epimerization catalyzed by tin-organic frameworks [PDF]
Current Research in Green and Sustainable ChemistryEpimerization of readily available monosaccharides presents an atom-efficient approach to expand the portfolio of rare monosaccharides. Here, we report tin-organic frameworks (Sn-OF) as a highly selective catalyst for synthesis of rare monosaccharides ...
Valérie Toussaint +3 more
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Epimerization-free C-term Activation of Peptide Fragments by Ball-Milling [PDF]
, 2020 Ball-milling enabled to perform [2+1], [2+2], and [2+3] peptide couplings with high yields and, if any, very low epimerization. Very good results were obtained with peptide fragments containing highly epimerization-prone and/or highly hindered amino ...
Marion, Jean +5 more
core +3 more sources
The Kinetic Stereocontrol in Brøsted Acid-catalyzed Pictet-Spengler Reaction and the Dynamic Epimerization Mechanism via Crystallization-induced Diastereomer Transformations [PDF]
, 2023 The merging of asymmetric catalysis with crystallization-induced diastereomer transformations (CIDTs) shows promise as a practical method for the synthesis of chiral molecules with one or more epimerization carbons.
Liuqun, Gu
core +1 more source
Visible-Light-Mediated, Diastereoselective Epimerization of Exocyclic Amines [PDF]
, 2023 Stereoselective α-amino C–H epimerization of exocyclic amines is achieved via photoredox catalyzed, thiyl-radical mediated, reversible hydrogen atom transfer to provide thermodynamically controlled anti/syn isomer ratios.
Aidan S. Liu (17710194) +2 more
core +1 more source
Molecules, 2022 l-Hexoses are important components of biologically relevant compounds and precursors of some therapeuticals. However, they typically cannot be obtained from natural sources and due to the complexity of their synthesis, their commercially available ...
Fruzsina Demeter +3 more
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Toxins, 2023 Deoxynivalenol (DON), one of the main mycotoxins with enteric toxicity, genetic toxicity, and immunotoxicity, and is widely found in corn, barley, wheat, and rye.
Yuqian Tang, Dingna Xiao, Chendi Liu
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Porous Tin-Organic Frameworks as Selective Epimerization Catalysts in Aqueous Solutions [PDF]
, 2023 Epimerization of sugars is a carbon-efficient route not only to produce rare carbohydrates but also to extend the product scope for chemical production in future biorefineries.
Willms, Andrea +3 more
core +1 more source
Epimerization-Free Preparation of C‑Terminal Cys Peptide Acid by Fmoc SPPS Using Pseudoproline-Type Protecting Group [PDF]
, 2019 Preparation of C-terminal Cys-containing peptide acid by Fmoc solid-phase peptide synthesis (SPPS) is difficult due to base-mediated epimerization at Cys.
Shun Masuda (7592351) +2 more
core +1 more source
Microorganisms, 2021 Clostridioides difficile is an anaerobic pathogen that causes significant morbidity and mortality. Understanding the mechanisms of colonization resistance against C. difficile is important for elucidating the mechanisms by which C.
Amber D. Reed, Casey M. Theriot
doaj +1 more source