Results in Engineering, 2022 Herein, we report a simple synthetic protocol for selective epoxidation of olefins, monocyclic terpenes, and chalcones using a continuous semi-batch process in good to excellent yields.
Chidambaram R. Ramaswamy +7 more
doaj +1 more source
Kinetic Resolution in Asymmetric Epoxidation using Iminium Salt Catalysis [PDF]
, 2013 The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis ...
Allin, Steven M. +7 more
core +1 more source
Epoxidation of Soybean Oil and its Blend with Waste Cooking Oil Using H2SO4 as Homogeneous Catalyst
Chemical Engineering Transactions, 2023 Epoxidation of soybean oil is carried out at different conditions such as the feed ratio of C=C/CH3COOH/H2O2 (1:1:1, 1:1:2, 1:2:1, 1:2:2, 1:2:4), reaction temperature (50 °C, 65 °C) and reaction time (3–7 h). Physicochemical properties of the reagent and
Hong-Phuong Phan +2 more
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Kinetic models of reaction systems for the in situ epoxidation of unsaturated fatty acid esters and triglycerides [PDF]
Hemijska Industrija, 2004 Mathematical models that describe the kinetics of reaction systems for the in situ epoxidation of unsaturated fatty acid esters or triglycérides with organic peracids are reviewed in this paper. The advantages and inadequacies of each model are discussed.
Janković Milovan R. +1 more
doaj +1 more source
Epoxidação do óleo de soja com o sistema catalítico [MoO2(acac)2]/TBHP EM [bmim][PF6]
Química Nova, 2012 Epoxidation of soybean oil was investigated using 1-n-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6] ionic liquid as biphasic medium with molybdenum(VI) acetylacetonate complex and tert-butyl hydroperoxide TBHP as oxidizing agent.
Maritana Farias, Márcia Martinelli
doaj +1 more source
FORMULASI PEMBUATAN BIOGREASE DENGAN BASE OIL EPOKSI RBDPO
Jurnal Teknologi Industri Pertanian, 2021 Biogrease is a semi-solid lubricant produced using vegetable oil. The biogrease consists of base oil and thickening agent. Base oil modification is done to change properties such as viscosity, adhesive properties to iron, etc.
M Luqmanul Hakim +2 more
doaj +1 more source
Rational design of a polyoxometalate intercalated layered double hydroxide: highly efficient catalytic epoxidation of allylic alcohols under mild and solvent-free conditions [PDF]
, 2016 Intercalation catalysts, owing to their modular and accessible gallery and unique interlamellar chemical environment, have shown wide application in various catalytic reactions.
Chen, Wei +4 more
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Catalysts, 2021 Terpene epoxides are considered as potential primary intermediates in the synthesis of numerous green polymers including epoxy resins, polycarbonates, nonisocyanate polyurethanes and even some polyamides.
Yacoub Mahamat Ahmat +3 more
semanticscholar +1 more source
Журнал органічної та фармацевтичної хімії, 2019 Aim. To study the kinetics of the epoxidation reaction for eugenol and isoeugenol with perbenzoic acid, carry out the comparative quantum chemical study of the epoxidation reaction mechanism of eugenol and isoeugenol isomers (2-cis and 2-trans) with ...
O. M. Agafonov +2 more
doaj +1 more source
Modification of chiral dimethyl tartrate through transesterification : immobilisation on POSS and enantioselectivity reversion in Sharpless asymmetric epoxidation [PDF]
, 2010 Modification of dimethyl tartrate has been investigated through transesterification with aminoalcohols to provide reactive functionalities for the covalent bonding of chiral tartrate to polyhedral oligomeric silsesquioxanes.
García, Rafael A. +4 more
core +1 more source