Results 41 to 50 of about 59,417 (298)

Enantioconvergent Cobalt‐Catalyzed Hydroalkylation for the Construction of Fluoro, Chloro, and Trifluoromethyl Stereogenic Centers

open access: yesAngewandte Chemie, EarlyView.
Cobalt‐hydride catalyzed enantioconvergent hydroalkylation with allenes and alkenes is achieved with high chemo‐, regio‐, and enantioselectivity. This method allows the streamlined synthesis of enantiomerically enriched C(sp3)–fluorine, –chlorine, and –trifluoromethyl stereocenters.
Uttam Dhawa, Xile Hu
wiley   +2 more sources

Characterization, kinetics and thermodynamics of epoxidation-esterification of Irvingia gabonensis kernel oil methyl ester

open access: yesHeliyon, 2022
Epoxidation-esterification of fatty acid methyl ester obtained from Irvingia gabonensis kernel oil (IGKO), as well as its characterization, kinetics and thermodynamics were the main focus of this study.
C.M. Agu   +5 more
doaj  

Metal-organic frameworks as selective or chiral oxidation catalysts [PDF]

open access: yes, 2014
Since the discovery of Metal Organic Frameworks (MOFs) in the early 1990s, the amount of new structures has grown exponentially. A MOF typically consists of inorganic nodes that are connected by organic linkers to form crystalline, highly porous ...
Leus, Karen   +2 more
core   +1 more source

Epoxidation of Argemone mexicana oil with peroxyacetic acid formed in-situ using sulfated tin (IV) oxide catalyst: Characterization; kinetic and thermodynamic analysis

open access: yesHeliyon, 2023
In this study, sulfated tin (IV) oxide solid acid catalyst was prepared for the epoxidation of Argemone mexicana oil (AMO) with peroxyacetic acid formed in-situ.
Fekadu Ashine   +3 more
doaj  

Catalytic and mechanistic studies into the epoxidation of styrenes using manganese complexes of structurally similar polyamine ligands [PDF]

open access: yes, 2014
The synthesis and catalytic activity of manganese(ii) complexes of two polyamine ligands is reported which highlights how a small structural change in the ligand affects the overall catalytic behaviour.
Al-Safadi, R   +5 more
core   +1 more source

Cloisite 15Aº nanoclay as an effective PTC for the epoxidation of hydroxyl terminated polybutadiene (HTPB)

open access: yesPolímeros, 2014
A simple method is reported for the epoxidation of hydroxyl-terminated polybutadiene (HTPB) by using in-situ generated dimethyl dioxirane (DMD) as an oxidant and Cloisite 15Aº nanoclay as a phase-transfer catalyst (PTC).
Mir Mohammad Alavi Nikje   +1 more
doaj   +1 more source

Lactose as an inexpensive starting material for the preparation of aldohexos-5-uloses: synthesis of L-ribo and D-lyxo derivatives [PDF]

open access: yes, 2010
SUMMARY: Partially protected derivatives of L-ribo- and D-lyxo-aldohexos-5-ulose have been prepared starting from triacetonlactose dimethyl acetal derivatives.
Catelani, Giorgio   +2 more
core   +1 more source

Epoxides and Soluble Epoxide Hydrolase in Cardiovascular Physiology [PDF]

open access: yesPhysiological Reviews, 2012
Epoxyeicosatrienoic acids (EETs) are arachidonic acid metabolites that importantly contribute to vascular and cardiac physiology. The contribution of EETs to vascular and cardiac function is further influenced by soluble epoxide hydrolase (sEH) that degrades EETs to diols. Vascular actions of EETs include dilation and angiogenesis.
openaire   +3 more sources

The remarkable catalytic activity of the saturated metal organic framework V-MIL-47 in the cyclohexene oxidation [PDF]

open access: yes, 2010
The remarkable catalytic activity of the saturated metal organic framework MIL-47 in the epoxidation of cyclohexene is elucidated by means of both experimental results and theoretical ...
Leus, Karen   +6 more
core   +2 more sources

Photoenzymatic epoxidation of styrenes

open access: yesChemical Communications, 2019
Photochemical reduction of flavin adenine dinucleotide (FAD) enables the direct, non-enzymatic regeneration of styrene monooxygenase for enantiospecific epoxidation reactions.
Morten M. C. H. van Schie   +3 more
openaire   +6 more sources

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