Results 51 to 60 of about 41,666 (217)

Kinetic and chemorheological modeling of thermosetting polyurethanes obtained from an epoxidized soybean oil polyol crosslinked with glycerin [PDF]

open access: yesarXiv, 2022
Thermosetting polyurethanes were obtained using an aromatic isocyanate and a hydrophobic polyol formulation obtained from epoxidized soybean oil (ESO) crosslinked with glycerin. A systematic DSC analysis of the effect of catalyst type, crosslinker concentration, isocyanate index and ESO crystallization on the cure kinetics was conducted.
arxiv  

Metal-organic frameworks as selective or chiral oxidation catalysts [PDF]

open access: yes, 2014
Since the discovery of Metal Organic Frameworks (MOFs) in the early 1990s, the amount of new structures has grown exponentially. A MOF typically consists of inorganic nodes that are connected by organic linkers to form crystalline, highly porous ...
Leus, Karen   +2 more
core   +1 more source

Epoxidation of Argemone mexicana oil with peroxyacetic acid formed in-situ using sulfated tin (IV) oxide catalyst: Characterization; kinetic and thermodynamic analysis

open access: yesHeliyon, 2023
In this study, sulfated tin (IV) oxide solid acid catalyst was prepared for the epoxidation of Argemone mexicana oil (AMO) with peroxyacetic acid formed in-situ.
Fekadu Ashine   +3 more
doaj  

Attempted Synthesis of Vinca Alkaloids Condensed with Three-Membered Rings

open access: yesMolecules, 2018
Our successful work for the synthesis of cyclopropanated vinblastine and its derivatives by the Simmons–Smith reaction was followed to build up further three-membered rings into the 14,15-position of the vindoline part of the dimer alkaloid ...
András Keglevich   +8 more
doaj   +1 more source

Probing the Thermal Deoxygenation of Graphene Oxide using High Resolution In Situ X-Ray based Spectroscopies [PDF]

open access: yesThe Journal of Physical Chemistry C, 2011, 115, 17009-17019, 2011
Despite the recent developments in Graphene Oxide due to its importance as a host precursor of Graphene, the detailed electronic structure and its evolution during the thermal reduction remain largely unknown, hindering its potential applications.
arxiv   +1 more source

In situ formation of catalytically active graphene in ethylene photo-epoxidation. [PDF]

open access: yes, 2018
Ethylene epoxidation is used to produce 2 × 107 ton per year of ethylene oxide, a major feedstock for commodity chemicals and plastics. While high pressures and temperatures are required for the reaction, plasmonic photoexcitation of the Ag catalyst ...
Heo, Jaeyoung   +3 more
core   +1 more source

Photoenzymatic epoxidation of styrenes

open access: yesChemical Communications, 2019
Photochemical reduction of flavin adenine dinucleotide (FAD) enables the direct, non-enzymatic regeneration of styrene monooxygenase for enantiospecific epoxidation reactions.
Morten M. C. H. van Schie   +3 more
openaire   +6 more sources

Characterization, kinetics and thermodynamics of epoxidation-esterification of Irvingia gabonensis kernel oil methyl ester

open access: yesHeliyon, 2022
Epoxidation-esterification of fatty acid methyl ester obtained from Irvingia gabonensis kernel oil (IGKO), as well as its characterization, kinetics and thermodynamics were the main focus of this study.
C.M. Agu   +5 more
doaj  

The remarkable catalytic activity of the saturated metal organic framework V-MIL-47 in the cyclohexene oxidation [PDF]

open access: yes, 2010
The remarkable catalytic activity of the saturated metal organic framework MIL-47 in the epoxidation of cyclohexene is elucidated by means of both experimental results and theoretical ...
Leus, Karen   +6 more
core   +2 more sources

Epoxidação do óleo de mamona e derivados empregando o sistema catalítico VO(acac)2/TBHP Epoxidation of castor oil and its derivatives using VO(acac)2/TBHP as the catalytic system

open access: yesQuímica Nova, 2008
The alternative system VO(acac)2/TBHP was investigated for the epoxidation reaction of castor oil and its derivatives. Results of 88% of conversion, 73% of epoxidation and 82% of selectivity were obtained for the system containing 20% excess of TBHP and ...
Marta Regina dos Santos Nunes   +2 more
doaj   +1 more source

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