Results 151 to 160 of about 165,305 (402)

Comparison of Curing Efficacy of Halogen and LED Polymerization Lamps Using Composite Materials of Different Polymerization Mechanism

open access: yesČeská Stomatologie a Praktické Zubní Lékařství, 2009
The objective was to compare efficacy of several types of halogen and LED polymerization lamps in curing restorative composite materials. Halogen lamps Heliolux DLX1 (Ivoclar Vivadent) and Megalux Fast Cure (MegaPhysik) and LED lamps DioPower (CMS Dental)
P. Bradna   +3 more
doaj  

Epoxidation of flavones by dimethyldioxirane

open access: yesThe Journal of Organic Chemistry, 1991
The synthesis of epoxides 2 by epoxydation of flavones 1 with isolated dimethyldioxirane (as acetone solution) at subambient temperatures is reported. These labile epoxides were isolated and completely characterized by UV, IR, 1 H and 13 C NMR, MS, and C, H analyses.
Adam, W.   +3 more
openaire   +3 more sources

Synthesis of a Molecular Tweezer Based on Norbornadiene Framework: Unexpected Stereoselectivity

open access: yesAsian Journal of Organic Chemistry, EarlyView.
A new type of Klarner's molecular tweezer was synthesized through annulation of an α‐amino ketone. Surprisingly, the reaction takes place stereoselectivity though the initial amino ketone is racemic. This tweezer comprises two near‐parallel flat aromatic rings as pincers, each bearing two methyl ester groups, and a pyrazine unit as the tether ...
Evren Cücü   +3 more
wiley   +1 more source

Epipolythiodioxopiperazine‐Based Natural Products: Building Blocks, Biosynthesis and Biological Activities

open access: yesChemBioChem, Volume 23, Issue 23, December 5, 2022., 2022
Housing sulfur: Certain fungi produce diketopiperazine compounds with a transannular sulfur bridge. These so‐called epipolythiodioxopiperzines are toxic by non‐specifically interacting with intracellular proteins and contribute to fungal pathogenicity. Producer strains serve as bio‐pesticides but also question safety of food fermentation.
Eva M. Huber
wiley   +1 more source

Concise Total Syntheses of Leuconoxine‐Type Alkaloids Enabled by Palladium/Norbornene‐Catalyzed Pyrrole Difunctionalization

open access: yesAngewandte Chemie, EarlyView.
Concise total syntheses of five leuconoxine alkaloids have been achieved using a pyrrole‐centered strategy, which features a newly developed palladium/norbornene‐catalyzed pyrrole double C─H functionalization method, a divergent late‐stage oxidative dearomatization tactic, and no use of protecting groups.
Xin Liu   +5 more
wiley   +2 more sources

Cross metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks

open access: yesBeilstein Journal of Organic Chemistry, 2015
The cross metathesis of 1,2-epoxy-5-hexene (1) with methyl acrylate and acrylonitrile was investigated as an entry to the synthesis of polyfunctional compounds.
Meriem K. Abderrezak   +6 more
doaj   +1 more source

Ozone adsorption on graphene: ab initio study and experimental validation [PDF]

open access: yesarXiv, 2009
We have investigated ozone adsorption on graphene using the ab initio density functional theory method. Ozone molecules adsorb on graphene basal plane with binding energy of 0.25 eV, and the physisorbed molecule can chemically react with graphene to form an epoxide group and an oxygen molecule.
arxiv  

Graphene Oxide‐Based Gene Modulation in Preferential Elimination of Lung Cancer Cells in a 3D Tumor Microenvironment Model

open access: yesAdvanced NanoBiomed Research, EarlyView.
Chemically modified graphene oxide nanocarriers provide a targeted lung cancer gene therapy platform. In a 3D tumor microenvironment model, these nanocarriers deliver therapeutic genes, regulate immune markers, and induce apoptosis in cancer cells. Combined gene delivery enhances cancer cell elimination, demonstrating the potential of this approach for
Francesca Grilli   +3 more
wiley   +1 more source

Engineering 2‐Deoxy‐D‐ribose‐5‐phosphate Aldolase for anti‐ and syn‐Selective Epoxidations of α,β‐Unsaturated Aldehydes

open access: yesAngewandte Chemie, EarlyView.
The anti‐ and syn‐selective epoxidation of various α,β‐unsaturated aldehydes is promoted by an engineered variant of 2‐deoxy‐D‐ribose‐5‐phosphate aldolase (DERA), giving rise to various α,β‐epoxy‐aldehydes with excellent enantiopurity (enantiomeric ratio up to 99 : 1). Abstract The enzyme 2‐deoxy‐D‐ribose‐5‐phosphate aldolase (DERA) naturally catalyzes
Hangyu Zhou   +5 more
wiley   +2 more sources

A chemical platform approach on cardanol oil: from the synthesis of building blocks to polymer synthesis

open access: yesOilseeds and fats, crops and lipids, 2016
This review proposes a platform approach for the synthesis of various building blocks from cardanol oil in one or two-steps synthesis. Cardanol is a natural phenol issued from Cashew nutshell liquid (CNSL).
Jaillet Fanny   +3 more
doaj   +1 more source

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