Enantioselective Synthesis of 2,2-Disubstituted Terminal Epoxides via Catalytic Asymmetric Corey-Chaykovsky Epoxidation of Ketones [PDF]
Molecules, 2012 Catalytic asymmetric Corey-Chaykovsky epoxidation of various ketones with dimethyloxosulfonium methylide using a heterobimetallic La-Li3-BINOL complex (LLB) is described.
Shigeki Matsunaga +3 more
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Trichloroisocyanuric Acid: An Alternate Green Route for the Transformation of Alkenes into Epoxides [PDF]
Journal of the Brazilian Chemical Society, 2002 The preparation of epoxides is efficiently achieved in mild conditions by reaction of alkenes with trichloroisocyanuric acid in aqueous acetone followed by treatment of the resulting chlorohydrin with aqueous KOH in ether / pentane.
Wengert Mira +2 more
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Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 2023 The reaction mechanism of several Williamson‟s ether syntheses have been studied using density functional theory with triple-ζ basis sets. These computations show that the synthesis of geometrically-strained epoxide from deprotonated halohydrins is due ...
Pedro J. Silva
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Substituted Epoxides by Lithiation of Terminal Epoxides [PDF]
Organic Letters, 2004 AbstractFor Abstract see ChemInform Abstract in Full Text.
Hodgson, D, Reynolds, N, Coote, S
openaire +2 more sources
Deep Eutectic Solvents as Catalysts for Cyclic Carbonates Synthesis from CO2 and Epoxides
Molecules, 2022 In recent years, the chemical industry has put emphasis on designing or modifying chemical processes that would increasingly meet the requirements of the adopted proecological sustainable development strategy and the principles of green chemistry.
Dorota Mańka, Agnieszka Siewniak
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In situ epoxide generation by dimethyldioxirane oxidation and the use of epichlorohydrin in the flow synthesis of a library of β-amino alcohols [PDF]
Royal Society Open Science, 2018 The flow coupling of epichlorohydrin with substituted phenols, while efficient, limits the nature of the epoxide available for the development of focused libraries of β-amino alcohols.
Peter J. Cossar +3 more
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Journal of Lipid Research, 2022 In light of the importance of epoxyeicosatrienoic acids (EETs) in mammalian pathophysiology, a nonenzymatic route that might form these monoepoxides in cells is of significant interest.
James A. Weiny +4 more
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Molecules, 2019 Most of the current amine hardeners are petro-sourced and only a few studies have focused on the research of bio-based substitutes. Hence, in an eco-friendly context, our team proposed the design of bio-based amine monomers with aromatic structures. This
Anne-Sophie Mora +4 more
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Si-Imidazole-HSO4 Functionalized Magnetic Fe3O4 Nanoparticles as an Efficient and Reusable Catalyst for the Regioselective Ring Opening of Epoxides in Water [PDF]
Nanochemistry Research, 2016 An efficient and simple method for the preparation of Si-Imidazole-HSO4 functionalized magnetic Fe3O4 nanoparticles (Si-Im-HSO4 MNPs) and used as an efficient and reusable magnetic catalysts for the regioselective ring opening of epoxides under green ...
Eshagh Rezaee Nezhad +1 more
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The Ability of NCP@POCl2-x Core-Shell Magnetic Nano-Catalyst for Simultaneous Conversion of Epoxides into Cyanohydrin and α,β-Unsaturated Carboxylic Acid [PDF]
Journal of Optoelectronical Nanostructures: This paper presents a new environmental, and remarkably efficient heterogeneous magnetic nanocomposite, NCP@POCl2-x (Fe3O4@SiO2@CS@POCl2-x), designed for the regioselective production of cyanide compounds from epoxides using NaCN, subsequently ...
Farzaneh Ebrahimzadeh
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