Total synthesis of aurofusarin: studies on the atropisomeric stability of bis-naphthoquinones [PDF]
An efficient annulation involving pyrone addition to a quinone and Dieckmann condensation was developed for rapid assembly of a γ-naphthopyrone monomeric precursor to the bis-naphthoquinone natural product aurofusarin.
Allen+42 more
core +1 more source
Supramolecular Chemistry in Metal–Organic Framework Materials
This review highlights synergies between reticular chemistry and supramolecular chemistry. The role of supramolecular interactions in determining framework…guest interactions and attempts to understand dynamic behavior in metal–organic frameworks (MOFs), particularly emphasizing the development of crystal sponges, studying reactions in frameworks and ...
Eugenia Miguel‐Casañ+3 more
wiley +1 more source
Cross metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks
The cross metathesis of 1,2-epoxy-5-hexene (1) with methyl acrylate and acrylonitrile was investigated as an entry to the synthesis of polyfunctional compounds.
Meriem K. Abderrezak+6 more
doaj +1 more source
CF3-Bis-TEMPO-Vis: New Visible Light Active Bis-Benzimidazolequinone Alkoxyamine
Alkoxyamines of TEMPO usually dissociate thermally at >100 °C; however, room temperature homolysis, activated by visible light, occurs with benzimidazolequinone derivatives.
Patrick Kielty+3 more
doaj +1 more source
Liquid Metal‐Vitrimer Conductive Composite for Recyclable and Resilient Electronics
To address the growing electronic waste challenge, an electrically conductive, healable, and recyclable plastic composite is created, composed of vitrimer and liquid metal microdroplets. A reconfigurable circuit board is demonstrated using this composite material, providing a notable step toward sustainable and robust electronic technologies.
Dong Hae Ho+4 more
wiley +1 more source
Acute Hypercapnia/Ischemia Alters the Esterification of Arachidonic Acid and Docosahexaenoic Acid Epoxide Metabolites in Rat Brain Neutral Lipids. [PDF]
In the brain, approximately 90% of oxylipins are esterified to lipids. However, the significance of this esterification process is not known. In the present study, we (1) validated an aminopropyl solid phase extraction (SPE) method for separating ...
Bazinet, Richard P+7 more
core +1 more source
Genotoxicity assessment of piperitenone oxide: an in vitro and in silico evaluation [PDF]
Piperitenone oxide, a natural flavouring agent also known as rotundifolone, has been studied for the genotoxicity assessment by an integrated in vitro and in silico experimental approach, including the bacterial reverse mutation assay, the micronucleus ...
Abete, Lorena+9 more
core +1 more source
Chemical looping epoxidation of ethylene was demonstrated, whereby the sole oxidant was a solid oxygen carrier, 15 wt% Ag supported on SrFeO3. Ethylene reacted with a bed of carrier particles, without any O2(g) in the feed, to produce ethylene oxide (EO) and CO2.
Chan, MSC+3 more
openaire +2 more sources
Recent Advances in Heterogeneous Frustrated Lewis Pair: Synthesis, Characterization, and Catalysis
This review provides a concise analysis of heterogeneous frustrated Lewis pair (FLP) chemistry, focusing on their synthesis, characterization, and application in small‐molecule activation. It highlights current challenges in developing solid FLP systems and explores promising advancements through emerging technologies, offering critical insights into ...
Jiasi Li+2 more
wiley +1 more source
This review proposes a platform approach for the synthesis of various building blocks from cardanol oil in one or two-steps synthesis. Cardanol is a natural phenol issued from Cashew nutshell liquid (CNSL).
Jaillet Fanny+3 more
doaj +1 more source