Results 91 to 100 of about 45,811 (284)

Estimating the compressive strength of lightweight foamed concrete using different machine learning-based symbolic regression techniques

open access: yesFrontiers in Built Environment
The development of concrete with excellent water and frost resistance providing high level of sound and thermal insulation has triggered the formulation of foamed concrete.
Kennedy C. Onyelowe   +9 more
doaj   +1 more source

Production of oriented nitrogen-vacancy color centers in synthetic diamond

open access: yes, 2011
The negatively charged nitrogen-vacancy (NV-) center in diamond is an attractive candidate for applications that range from magnetometry to quantum information processing. Here we show that only a fraction of the nitrogen (typically < 0.5 %) incorporated
Beausoleil, R. G.   +8 more
core   +1 more source

Nanocurvature‐Activated Dipolar Polarization in M–N4 Single‐Atom Sites for High‐Performance Electromagnetic Wave Absorption

open access: yesAdvanced Science, EarlyView.
Increasing nanocurvature effectively enriches the local electron density of the M–N4 motif, which facilitates electron transfer from the metal center to nitrogen atoms. This electronic behavior intensifies the localization and asymmetric distribution of charge, thereby significantly amplifying the dipole moment and polarizability.
Daohu Sheng   +7 more
wiley   +1 more source

Monitoring Redox Pathways and Performance Limitations in Lithium‐Sulfur Batteries Using In Situ 7/6Li and 33S NMR Spectroscopies

open access: yesAngewandte Chemie, EarlyView.
Lithium‐sulfur (Li‐S) batteries contain various NMR‐active nuclear isotopes, including 7Li, 6Li and 33S, which are sensitive to the different chemical reactions that occur during battery cycling. Herein, we use a combination of lithium and sulfur operando NMR spectroscopy to provide new insights at the molecular level, fundamental understanding being ...
Jana B. Fritzke   +7 more
wiley   +2 more sources

Relational EPR

open access: yes, 2006
We study the EPR-type correlations from the perspective of the relational interpretation of quantum mechanics. We argue that these correlations do not entail any form of 'non-locality', when viewed in the context of this interpretation.
A. Aspect   +26 more
core   +5 more sources

Photodynamic Priming and Minocycline Overcome Chemoresistance by Reprogramming the Pancreatic Tumor Immune Microenvironment In Vivo

open access: yesAdvanced Science, EarlyView.
Dual priming with minocycline and photodynamic priming reprograms the pancreatic tumor microenvironment to overcome chemoresistance. By suppressing DNA repair enzyme Tdp1, inducing photooxidative damage, and enhancing irinotecan delivery via light‐activated nanoencapsulation, this strategy remodels the tumor microenvironment and drives immune ...
Fernanda V. Cabral   +7 more
wiley   +1 more source

From [NHC─H]• to Persistent σ‐Complex Radicals: Photoinduced Radical Chemistry of Imidazolium Salts

open access: yesAngewandte Chemie, EarlyView.
Visible‐light excitation of electron donor–acceptor (EDA) complexes between imidazolium salts and triarylamines enables controlled single‐electron transfer (SET) and reveals a family of carbene‐centered σ‐complex radical cations. Cryogenic electron paramagnetic resonance (EPR) captures the elusive [NHC─H]• intermediate and its thermal evolution into ...
Filipp M. Kolomeychuk   +4 more
wiley   +2 more sources

Recent Advances in Nano‐Microstructured Catalysts for Electrochemical Seawater Electrocatalysis

open access: yesAdvanced Energy Materials, EarlyView.
This review highlights advances in nano‐ and microstructured catalysts for electrochemical seawater conversion. It elucidates design principles, mechanistic understanding, and machine‐learning‐assisted discovery, and outlines key challenges and future opportunities toward efficient, selective, and durable seawater electrocatalysis.
Xiaodong Shao   +5 more
wiley   +1 more source

Site‐Selective B─H Activation via HAT Toward Xanthyl‐closo‐Carboranes as Bench‐Stable Precursors of Organosulfur Boron Clusters

open access: yesAngewandte Chemie, EarlyView.
A light mediated direct regioselective B─H functionalization, via hydrogen atom transfer (HAT), is described. Unexplored xanthyl‐closo‐carboranes as novel bench‐stable and versatile platforms to access sulfur‐containing boron clusters are reported for the first time.
Marco Rusconi   +9 more
wiley   +2 more sources

Electron Paramagnetic Resonance Spectroscopy

open access: yesCHIMIA, 2001
A survey of the activities of the EPR group at ETH is given. The different research areas are discussed briefly and a particular project is highlighted.
Carlos Calle   +14 more
doaj   +2 more sources

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