Results 241 to 250 of about 45,358 (304)

Phosphoryl Radicals from Trivalent Iminyl Phosphines: A Photocatalytic Approach to N‐Phosphoryl Azetidines

Angewandte Chemie, EarlyView.
Photochemically generated phosphoryl radicals from iminyl phosphines enable strain‐release addition to azabicyclobutanes, providing access to elusive N‐phosphoryl azetidines. Combined experimental, computational, and EPR studies reveal an unconventional water‐assisted photoredox pathway.
Chandu G. Krishnan, Gabriel Cormier, Stefano A. Serapian, Marco Bortolus, Luca Dell'Amico   +4 more
wiley   +1 more source

Conformational investigation of the asymmetric periplasmic domains of E. coli LptB₂FGC using SDSL CW EPR spectroscopy. [PDF]

Appl Magn Reson
Cina NP, Klug CS.
europepmc   +1 more source

Coordination of dissolved transition metals in pristine battery electrolyte solutions determined by NMR and EPR spectroscopy.

Phys Chem Chem Phys
Allen JP, Szczuka C, Smith HE, Jónsson E, Eichel RA, Granwehr J, Grey CP.   +6 more
europepmc   +1 more source

Metal-carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy. [PDF]

Chem Sci
Nodaraki LE, Liu J, Ariciu AM, Ortu F, Oakley MS, Birnoschi L, Gransbury GK, Cobb PJ, Emerson-King J, Chilton NF, Mills DP, McInnes EJL, Tuna F.   +12 more
europepmc   +1 more source

Elucidation of site-specific red-ox kinetics in the CO-assisted N₂O decomposition over Fe-ferrierite by combining modulation excitation with <i>operando</i> EPR spectroscopy. [PDF]

Chem Sci
Fischer JWA, Buttignol F, Garbujo A, Ferri D, Jeschke G.   +4 more
europepmc   +1 more source

Sigmatropic rearrangement enables access to a highly stable spirocyclic nitroxide for protein spin labelling.

Chem Commun (Camb)
Sowiński MP, Mocanu EM, Ruskin-Dodd H, McKay AP, Cordes DB, Lovett JE, Haugland-Grange M.   +6 more
europepmc   +1 more source

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In‐Cell NMR and EPR Spectroscopy of Biomacromolecules

Angewandte Chemie - International Edition, 2014
AbstractThe dream of cell biologists is to be able to watch biological macromolecules perform their duties in the intracellular environment of live cells. Ideally, the observation of both the location and the conformation of these macromolecules with biophysical techniques is desired.
Robert Hansel, Lukas Trantírek, Volker Dotsch   +2 more
exaly   +3 more sources

EPR Spectroscopy

, 2022
EPR spectroscopy is a versatile, nondestructive technique widely used in chemistry, biology, and physics. It detects molecules and materials with unpaired electrons making it a very selective technique that produces a wealth of information on such systems.
Doros T. Petasis
openaire   +2 more sources

EPR Spectroscopy in Catalysis

, 2011
The modern chemical industry relies heavily on homogeneous and heterogeneous catalysts. Understanding the operational mode, or reactivity, of these catalysts is crucial for improved developments and enhanced performance. As a result, various spectroscopic techniques are inevitably used to characterize and interrogate the mechanistic details of the ...
Van Doorslaer, Sabine, Murphy, Damien M.
openaire   +4 more sources

Perspectives of shaped pulses for EPR spectroscopy

Journal of Magnetic Resonance, 2017
This article describes current uses of shaped pulses, generated by an arbitrary waveform generator, in the field of EPR spectroscopy. We show applications of sech/tanh and WURST pulses to dipolar spectroscopy, including new pulse schemes and procedures, and discuss the more general concept of optimum-control-based pulses for applications in EPR ...
Philipp E Spindler, Wolfgang Kallies, Steffen J Glaser   +2 more
exaly   +3 more sources