Results 71 to 80 of about 83,419 (283)

Transition From Lattice Oxygen to Radical‐Mediated Oxidation in Ammonium‐Intercalated Birnessite Catalysts for Selective Valorization of Biomass to Produce Formic Acid

open access: yesAdvanced Functional Materials, EarlyView.
The catalytic valorization of biomass represents an essential approach for achieving sustainable chemical production, with formic acid (FA) being recognized as a valuable platform chemical for hydrogen storage and environmentally friendly synthetic applications.
Yiqi Geng   +6 more
wiley   +1 more source

Highly-Efficient Charge Separation and Polaron Delocalization in Polymer-Fullerene Bulk-Heterojunctions: A Comparative Multi-Frequency EPR & DFT Study

open access: yes, 2013
The ongoing depletion of fossil fuels has led to an intensive search for additional renewable energy sources. Solar-based technologies could provide sufficient energy to satisfy the global economic demands in the near future.
Banks, Brian P.   +10 more
core   +1 more source

Spin properties of dense near-surface ensembles of nitrogen-vacancy centres in diamond [PDF]

open access: yes, 2018
We present a study of the spin properties of dense layers of near-surface nitrogen-vacancy (NV) centres in diamond created by nitrogen ion implantation.
Broadway, D. A.   +10 more
core   +2 more sources

Suppression of Photo‐Mediated Traps in Integrated Organic Photovoltaic–Photodetector Devices via N‐Type Self‐Assembly‐Driven Interfacial Engineering

open access: yesAdvanced Functional Materials, EarlyView.
Conventional unstable electron transport layers (ETLs) limit self‐powered organic sensors. This work resolves this by developing a n‐type self‐assembled monolayer (SAM), “3‐PAPh”. This SAM forms a chemically stable and structurally ordered interface that fundamentally suppresses defect formation.
Ohhyun Kwon   +11 more
wiley   +1 more source

How can EPR spectroscopy help to unravel molecular mechanisms of flavin-dependent photoreceptors?

open access: yesFrontiers in Molecular Biosciences, 2015
Electron paramagnetic resonance (EPR) spectroscopy is a well-established spectroscopic method for the examination of paramagnetic molecules. Proteins can contain paramagnetic moieties in form of stable cofactors, transiently formed intermediates, or spin
Daniel eNohr   +3 more
doaj   +1 more source

Electron paramagnetic resonance of VN–VGa complex in BGaN

open access: yesAPL Materials, 2023
A metastable photoinduced electron paramagnetic resonance (EPR) signal at low temperatures is reported for GaN alloyed with boron (i.e., BxGa1−xN) epitaxial layers grown at temperatures ranging from 840 to 1090° C. An isotropic EPR line with g = 2.004 is
J. Kierdaszuk   +4 more
doaj   +1 more source

Spectroscopic characterization of the oxo-transfer reaction from a bis(µ-oxo)dicopper(III) complex to triphenylphosphine [PDF]

open access: yes, 2004
The oxygen-atom transfer reaction from the bis(µ-oxo)dicopper(III) complex [CuIII2(µ-O)2(L)2]2+1, where L =N,N,N,N -tetraethylethylenediamine, to PPh3 has been studied by UV-vis, EPR, 1H NMR and Cu K-edge X-ray absorption spectroscopy in parallel at low ...
Chan, Sunney I.   +2 more
core  

Low Temperature Photo-oxidation of Chloroperoxidase Compound II [PDF]

open access: yes, 2010
Oxidation of the heme-thiolate enzyme chloroperoxidase (CPO) from Caldariomyces fumago with peroxynitrite (PN) gave the Compound II intermediate, which was photo-oxidized with 365 nm light to give a reactive oxidizing species.
Bennett, Brian   +5 more
core   +2 more sources

Covalent Organic Frameworks for Photocatalytic CO2 Reduction: Metal Integration Principles, Strategies and Functions

open access: yesAdvanced Functional Materials, EarlyView.
Covalent organic frameworks (COFs) with metals have been recognized as versatile platforms for photocatalytic CO2 reduction (CO2PRR). Herein, an overview of metal integration strategies for COFs is systematically summarized. Regulatory mechanisms and structure–activity relationships between metal integration and COF‐based CO2PRR are emphasized.
Jie He   +5 more
wiley   +1 more source

Effect of microwave power on EPR spectra of natural and synthetic dental biocompatible materials

open access: yesNukleonika, 2015
Paramagnetic centers in the two exemplary synthetic and natural dental biocompatible materials applied in implantology were examined by the use of an X-band (9.3 GHz) electron paramagnetic resonance (EPR) spectroscopy.
Adamczyk Jakub   +2 more
doaj   +1 more source

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