Metal‐Free Electrophilic Borylative Cyclizations of Alkynes
Metal‐free borylative cyclizations based on electrophilic alkyne activation by boron Lewis acids provide efficient access to borylated hetero‐ and carbocycles. Early studies using B(C6F5)3 displayed limited scope and application, whereas recent ClBcat‐ and BCl3‐based methods enable mild CB and CC/CX bond formation for the synthesis of cycles ...
Jaime Mateos‐Gil +3 more
wiley +1 more source
One-step, efficient and sustainable microwave-assisted biodiesel production using a sulfonated porous organic polymer catalyst. [PDF]
Kaushik B +7 more
europepmc +1 more source
Unilateral mastication, a common oral habit, induces cognitive decline in rats by disrupting hippocampal cholesterol metabolism. It triggers astrocyte hyperplasia, enhances cholesterol synthesis, impairs transport/degradation, and reduces 24‐hydroxycholesterol (24‐OHC), ultimately damaging synaptic function.
Xiaoting Zhai +9 more
wiley +1 more source
Chemical Modification of Cellulose Fibers for Sustainable Food Packaging: Structure-Property-Sustainability Relationships. [PDF]
Kudzin MH +6 more
europepmc +1 more source
Advances in cholesterol and lipoproteins detection for healthcare: A review
Cholesterol is one of the main biomarkers related to the development of cardiovascular diseases. Its detection still relies on traditional methods of analysis, such as gas and liquid chromatographies. Detection of free cholesterol in saliva with redox or enzymatic sensors or detection of lipoproteins in blood with aptamer sensors are currently the most
Jacopo Giaretta +7 more
wiley +1 more source
A mild and atom-efficient four-component cascade strategy for the construction of biologically relevant 4-hydroxyquinolin-2(1<i>H</i>)-one derivatives. [PDF]
Grishin DA +13 more
europepmc +1 more source
Three poly(caprolactone) (PCL)‐based additives of differing molecular weights were used as a secondary plasticizer to prevent gas checks in PVC films produced through calendering. Results showed that chemical and physicochemical properties influence the prevention or reduction of gas checks, unlike rheological properties including complex viscosity and
Luis F. Alvarez +4 more
wiley +1 more source
Impact of Sorting and Catch Media on Porcine Sperm Motility, Capacitation, and Viability
ABSTRACT Background Fluorescence‐activated cell sorting (FACS) has emerged as a powerful tool for selecting spermatozoa of a desired population of fluorescent biomarkers, offering potential applications in reproductive biology and agriculture. However, concerns remain regarding sorting‐induced physiological alterations that could compromise spermatozoa
Tyler Weide, Juan Steibel, Karl Kerns
wiley +1 more source
A Mechanochemical Kolbe-Schmitt Reaction: Catechol Carboxylation Provides Building Blocks for Renewable Plasticizers. [PDF]
De Vos D +9 more
europepmc +1 more source

