Copper (II) bromide/NMO system for α-amination of esters in solvent-free condition [PDF]
Copper (II) bromide/ N-methylmorpholine N-oxide promoted α-amination of esters in solvent-free condition is reported. The α-amino esters are precursors for α-amino acids. This method provides α-amino esters in 58-83% yields.
Kankanala Naveen, Kumar +7 more
core +1 more source
Preparation of New 2,3-Diphenylpropenoic Acid Esters – Good Yields Even for the More Hindered Z Isomers [PDF]
The potassium salt of E- and Z-2,3-diphenylpropenoic acids prepared in situ could be esterified efficiently in DMSO with the appropriate alkyl halides at room temperature.
Boros, László +11 more
core +1 more source
Highly Diastereo- and Enantioselective Allylboration of Aldehydes using alpha-Substituted Allyl/Crotyl Pinacol Boronic Esters via in Situ Generated Borinic Esters [PDF]
Readily available, alpha-substituted allyl/crotyl pinacol boronic esters often give low E/Z selectivity (with Z favored) in reactions with aldehydes. We found that addition of nBuLi to the pinacol boronic ester followed by trapping of the alkoxide with ...
Jack L.‐Y. Chen +10 more
core +1 more source
Catalytic Deoxygenative Coupling of Aromatic Esters with Organophosphorus Compounds [PDF]
We have developed a deoxygenative coupling of aromatic esters with diarylphosphine oxides/dialkyl phosphonates under palladium catalysis. In this reaction, aromatic esters can work as novel benzylation reagents to give the corresponding benzylic ...
Miki B., Kurosawa +3 more
core +2 more sources
Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates [PDF]
This tutorial review highlights the organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium/azolium enolates.
Morrill, Louis C. +3 more
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Decarbonylative Reductive Coupling of Aromatic Esters by Nickel and Palladium Catalyst [PDF]
Ni or Pd-catalyzed decarbonylative reductive couplings of aromatic esters were developed. A range of (hetero)aromatic esters was applicable to these reductive homocoupling reactions.
Yunfei, Peng +7 more
core +2 more sources
Detectability of testosterone esters and estradiol benzoate in bovine hair and plasma following pour-on treatment [PDF]
The abuse of synthetic esters of natural steroids such as testosterone and estradiol in cattle fattening and sports is hard to detect via routine urine testing. The esters are rapidly hydrolysed in vivo into substances which are also endogenously present
Blokland, M.H. +17 more
core +1 more source
It is known that carboxyl groups bonded to aryl or hetaryl moieties play a role of the “pharmacophore” fragment in most NSAID molecules. It should be mentioned that the carboxyl group may cause the appearance of toxic effects and is characterized by ...
Viktor V. Stavytskyi +4 more
doaj +1 more source
Objectives. Due to their structures, pentaerythritol esters have a number of appealing properties such as high viscosity index when used as oils and excellent compatibility with polyvinyl chloride when used as plasticizers.
V. V. Emelyanov +4 more
doaj +1 more source
Glucosylation of Sucrose Laurate with Cyclodextrin Glucanotransferase [PDF]
Sucrose monolauroyl esters were found to serve as substrates for cyclodextrin glucanotransferase (CGTase)-catalyzed transglucosidation reactions, affording new sucrose esters that have an additional 1-3 glucose residues on the pyranose ring of the ...
Zhao, Haisuo +4 more
core +1 more source

