Scanning tunneling microscopy studies of monolayer templates: alkylthioethers and alkylethers [PDF]
Scanning tunneling microscopy has been used to determine the molecular ordering in stable, ordered monolayers formed from long-chain normal and substituted alkanes in solution on highly oriented pyrolytic graphite surfaces.
Brunschwig, Bruce S. +2 more
core +1 more source
Catalysis by alkali and alkaline-earth metal ions in nucleophilic attack of methoxide ion on crown ethers bearing an intra-annular acetoxy group [PDF]
Rates of reaction of methoxide ion with crown ethers bearing an intra-annular acetoxy group are markedly enhanced by alkali and alkaline-earth metal bromides as a result of much stronger interactions of the metal ions with transition states than with ...
Cacciapaglia, Roberta +5 more
core +3 more sources
Effect of base–acid properties of the mixtures of water with methanol on the solution enthalpy of selected cyclic ethers in this mixture at 298.15 K [PDF]
The enthalpies of solution of cyclic ethers: 1,4- dioxane, 12-crown-4 and 18-crown-6 in the mixture of water and methanol have been measured within the whole mole fraction range at T = 298.15 K.
A Wakisaka +56 more
core +2 more sources
Rate constants and Arrhenius parameters for the reactions of OH radicals and Cl atoms with CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, using the discharge-flow/resonance fluorescence method [PDF]
Rate constants have been determined for the reactions of OH radicals and Cl atoms with the three partially halogenated methyl-ethyl ethers, CF\(_3\)CH\(_2\)OCHF\(_2\), CF\(_3\)CHClOCHF\(_2\) and CF\(_3\)CH\(_2\)OCClF\(_2\), using discharge-flow ...
Beach, S. D. +3 more
core +1 more source
In this review, the latest achievements in the field of cationic polymerization of isobutylene catalyzed by the complexes of conventional Lewis acids with ethers are presented.
Sergei V. Kostjuk
doaj +1 more source
Thioether-catalysed tandem synthesis of furans and cyclic ethers or lactones [PDF]
Acyclic conjugated ynenediones tethered to an alcohol or carboxylic acid are converted into furanyl-substituted cyclic ethers or lactones in a single step by treatment with the tetrahydrothiophene.
Clark, J. Stephen, Klaus, Verena
core +1 more source
New synthetic phosphinate analogues of lecithin
The chemical syntheses of two new, completely nonhydrolyzable phosphinate analogues of lecithin are described. These have the structures ROCH2CH(OR)CH2CH2P(O)(O−)CH2CH2N+(CH3)3 and ROCH2CH(OR′)CH2P(O)(O−)CH2CH2CH2N+(CH3)3, where R = C18H37 and R ...
ARTHUR F. ROSENTHAL, SERGE V. CHODSKY
doaj +1 more source
Experimental and modeling study of the autoignition of 1-hexene/iso-octane mixtures at low temperatures [PDF]
Autoignition delay times have been measured in a rapid compression machine at Lille at temperatures after compression from 630 to 840 K, pressures from 8 to 14 bar, \Phi = 1 and for a iso octane/1 hexene mixture containing 82% iso-octane and 18% 1 hexene.
Barbé +33 more
core +3 more sources
Neurobehavioral function and low-level exposure to brominated flame retardants in adolescents : a cross-sectional study [PDF]
Background: Animal and in vitro studies demonstrated a neurotoxic potential of brominated flame retardants, a group of chemicals used in many household and commercial products to prevent fire.
Baeyens, Willy +12 more
core +1 more source
Transport of persistent organic pollutants across the human placenta [PDF]
Environment International 65, 107-115 ...
Fernández-Somoano, A +9 more
core +1 more source

