In situ generation of Mes2Mg as a non-nucleophilic carbon-centred base reagent for the efficient one-pot conversion of ketones to silyl enol ethers [PDF]
, 2008 Treatment of commercially available MesMgBr with 1,4-dioxane produces the key Mes2Mg reagent in situ which then mediates the deprotonation of ketones to deliver trimethylsilyl enol ethers, at readily accessible temperatures and without any nucleophilic ...
Hayes, Douglas. +2 more
core +1 more source
Transport of persistent organic pollutants across the human placenta [PDF]
, 2014 Environment International 65, 107-115 ...
Fernández-Somoano, A +9 more
core +1 more source
Modeling and Prediction of Coal Ash Fusion Temperature based on BP Neural Network
MATEC Web of Conferences, 2016 Coal ash is the residual generated from combustion of coal. The ash fusion temperature (AFT) of coal gives detail information on the suitability of a coal source for gasification procedures, and specifically to which extent ash agglomeration or ...
Miao Suzhen +4 more
doaj +1 more source
Gold Catalyzed Multicomponent Reactions beyond A3 Coupling
Molecules, 2018 The preparation of complex architectures has inspired the search for new methods and new processes in organic synthesis. Multicomponent reactions have become an interesting approach to achieve such molecular diversity and complexity.
Renso Visbal +3 more
doaj +1 more source
Cu/ZrO2 Catalyst Modified with Y2O3 for Effective and Stable Dehydration of Glycerol to Acetol
MoleculesGlycerol is a main by-product of biodiesel production, and its further processing is essential for the biorefinery. In this paper, a highly active and stable catalyst for the catalytic dehydration of glycerol to acetol is obtained by modifying a Cu-Zr ...
Zhoubing Liang +5 more
doaj +1 more source
Single-pass transformation of syngas into ethanol with high selectivity by triple tandem catalysis
Nature Communications, 2020 Direct synthesis of ethanol from non-petroleum carbon resources via syngas (CO/H2) is a highly attractive but challenging target. Here, the authors report a triple tandem catalytic system for single-pass conversion of syngas into ethanol with selectivity
Jincan Kang +7 more
doaj +1 more source
FEBS Letters, EarlyView.Atovaquone is an antimalarial requiring potentiation for sufficient efficacy. We pursued strategies to enhance its activity, showing that 4‐nitrobenzoate inhibits 4‐hydroxybenzoate polyprenyltransferase, decreasing ubiquinone biosynthesis. Since atovaquone competes with ubiquinol in mitochondria, 4‐nitrobenzoate facilitates its action, potentiating ...
Ignasi Bofill Verdaguer +7 more
wiley +1 more source
Catalytic tetrahydropyranylation of phenols and alcohols using vanadium(V)-substituted polyoxomolybdates [PDF]
Journal of the Serbian Chemical Society, 2012 Alcohols and phenols were tetrahydropyranylated in the presence of H7[PMo8V4O40] in good to excellent yields in acetonitrile and under solventfree reaction conditions.
Gharib Ali, Jahangir Manouchehr
doaj +1 more source
Results in Chemistry, 2021 An efficient process to prepare (3-indolyl)methyl ethers from various indoles and benzaldehydes under basic conditions was reported. The effects of bases, solvents were investigated.
Zubiao Zheng +6 more
doaj +1 more source
Vacuolar transport and function of Saccharomyces cerevisiae sterol ester hydrolase Tgl1
FEBS Letters, EarlyView.Tgl1, one of yeast sterol ester hydrolases, had been found on the lipid droplets where sterol esters are mainly stored. This study revealed that Tgl1 is transported into the vacuole depending on the ESCRT‐I–III complex, and that it exhibits intra‐vacuolar sterol ester hydrolase activity.
Takumi Nakatsuji +5 more
wiley +1 more source